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Russian Chemical Bulletin

, Volume 62, Issue 5, pp 1282–1285 | Cite as

Cyclic peroxides and related initiating systems for radical polymerization of methyl methacrylate

  • R. M. Islamova
  • O. I. Ishkinina
  • S. V. Nazarova
  • O. N. Chupakhin
  • I. A. Utepova
  • N. M. Andriyashina
  • A. O. Terent’ev
Full Articles

Abstract

Cyclic peroxides as initiators for the radical polymerization of methyl methacrylate were proposed. The initial rates, initiation rates, and effective activation energies of polymerization initiated by cyclic peroxides and cyclic peroxide-1-pyridyl-2-ferrocene systems were determined. The radical yields to the volume upon the thermal decomposition of cyclic peroxides and their catalytic decomposition in the presence of 1-pyridyl-2-ferrocene were determined. In combination with 1-pyridyl-2-ferrocene cyclic peroxides form efficient initiating systems favoring an increase in the polymerization rate, a decrease in the molecular weights, and an increase in syndiotacticity of the synthesized poly(methyl methacrylate).

Key words

radical polymerization cyclic peroxides initiators 1-pyridyl-2-ferrocene initiating systems kinetic parameters molecular characteristics 

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • R. M. Islamova
    • 1
    • 2
  • O. I. Ishkinina
    • 1
  • S. V. Nazarova
    • 1
  • O. N. Chupakhin
    • 3
  • I. A. Utepova
    • 3
  • N. M. Andriyashina
    • 1
  • A. O. Terent’ev
    • 4
  1. 1.Institute of Organic Chemistry, Ufa Scientific CenterRussian Academy of SciencesUfaRussian Federation
  2. 2.Bashkir State Agrarian UniversityUfaRussian Federation
  3. 3.Ural Federal University named after the First President of Russia B. N. YeltsinYekaterinburgRussian Federation
  4. 4.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation

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