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Influence of the supramolecular structure of the liquid reaction medium on the kinetics of acetone oxidation with aqueous solutions of nitric acid

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Abstract

Refined kinetic characteristics for the initial stage of acetone oxidation using purified nitric acid were obtained by dynamic calorimetry and NMR spectroscopy. The differences of obtained characteristics from the literature data are significant. The dependences of the 17O NMR spectra in the HNO3-H2O binary system and 1H NMR spectra in the ternary system with acetone on the reactant concentration were studied in detail. The character of the supramolecular structure of the reaction medium and its influence on the initial rate of acetone oxidation are discussed.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    G. B. Manelis, G. V. Lagodzinskaya, A. I. Kazakov, A. V. Chernyak, N. G. Yunda & L. S. Kurochkina

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  1. G. B. Manelis
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  2. G. V. Lagodzinskaya
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  3. A. I. Kazakov
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  4. A. V. Chernyak
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  5. N. G. Yunda
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  6. L. S. Kurochkina
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Corresponding author

Correspondence to G. V. Lagodzinskaya.

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Dedicated to the Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0994—1002, April, 2013.

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Manelis, G.B., Lagodzinskaya, G.V., Kazakov, A.I. et al. Influence of the supramolecular structure of the liquid reaction medium on the kinetics of acetone oxidation with aqueous solutions of nitric acid. Russ Chem Bull 62, 994–1002 (2013). https://doi.org/10.1007/s11172-013-0130-1

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  • DOI: https://doi.org/10.1007/s11172-013-0130-1

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