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Russian Chemical Bulletin

, Volume 62, Issue 3, pp 780–791 | Cite as

β-Diphenylphosphorylated alkanones and related compounds: synthesis and structure

  • E. I. Goryunov
  • G. V. Bodrin
  • I. B. Goryunova
  • Yu. V. Nelyubina
  • P. V. Petrovskii
  • T. V. Strelkova
  • A. S. Peregudov
  • A. G. Matveeva
  • M. P. Pasechnik
  • S. V. Matveev
  • E. E. Nifant’ev
Full Articles

Abstract

The reactions of diphenyl(diisopropyl)chlorophosphine with arylidene(heteroarylidene)-acetones and 3-benzylidenepentane-2,4-dione in the presence of acetic acid proceed at a high rate at room temperature to afford the corresponding β-diorganylphosphorylated alkanones and alkanediones in high yields. The reaction of diphenylchlorophosphine with 4-methoxybut-3-en-2-one and dibenzylideneacetone carried out under similar conditions at the equimolar reagent ratio can serve as a convenient method for the synthesis of unique β-diphenylphosphorylalkenones. The structures of compounds obtained were established by IR, Raman, and NMR spectroscopy and X-ray diffraction.

Key words

ylidene alkanones (alkanediones) chlorophosphines b-diorganylphosphorylalkanones (alkenones/alkanediones) synthesis IR Raman NMR spectra X-ray diffraction study 

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • E. I. Goryunov
    • 1
  • G. V. Bodrin
    • 1
  • I. B. Goryunova
    • 1
  • Yu. V. Nelyubina
    • 1
  • P. V. Petrovskii
    • 1
  • T. V. Strelkova
    • 1
  • A. S. Peregudov
    • 1
  • A. G. Matveeva
    • 1
  • M. P. Pasechnik
    • 1
  • S. V. Matveev
    • 1
  • E. E. Nifant’ev
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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