Regularities of the amino-Claisen rearrangement mechanism
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The synthetic and kinetic regularities of the amino-Claisen rearrangement (ACR) were studied for the transformation of 2,5-dimethyl-N-(pent-3-en-2-yl)aniline. The ACR products are formed due to the conversion of a binary π-complex formed by the reaction of N-alkenylaniline hydrochloride with hydrochloride of the solvent (2,5-dimethylaniline).
Key wordsClaisen rearrangement mechanism 2,5-dimethyl-N-(pent-3-en-2-yl)aniline
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