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Russian Chemical Bulletin

, Volume 62, Issue 1, pp 83–87 | Cite as

Regularities of the amino-Claisen rearrangement mechanism

  • I. B. Abdrakhmanov
  • I. M. Borisov
  • R. R. Ismagilov
  • N. G. Nigmatullin
  • R. N. Khusnitdinov
  • G. A. Tolstikov
Full Articles

Abstract

The synthetic and kinetic regularities of the amino-Claisen rearrangement (ACR) were studied for the transformation of 2,5-dimethyl-N-(pent-3-en-2-yl)aniline. The ACR products are formed due to the conversion of a binary π-complex formed by the reaction of N-alkenylaniline hydrochloride with hydrochloride of the solvent (2,5-dimethylaniline).

Key words

Claisen rearrangement mechanism 2,5-dimethyl-N-(pent-3-en-2-yl)aniline 

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References

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • I. B. Abdrakhmanov
    • 1
  • I. M. Borisov
    • 2
  • R. R. Ismagilov
    • 1
  • N. G. Nigmatullin
    • 3
  • R. N. Khusnitdinov
    • 1
  • G. A. Tolstikov
    • 4
  1. 1.Institute of Organic Chemistry, Ufa Scientific CenterRussian Academy of SciencesUfaRussian Federation
  2. 2.M. Akmulla Bashkir State Pedagogical UniversityUfaRussian Federation
  3. 3.Bashkir State Agrarian UniversityUfaRussian Federation
  4. 4.N. N. Vorozhtsov Novosibirsk Institute of Organic ChemistryNovosibirskRussian Federation

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