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Russian Chemical Bulletin

, Volume 61, Issue 9, pp 1776–1782 | Cite as

Synthesis of 1,6-dihydro-1,6-dihydroxybenzo[1,2-d:3,4-d′]bistriazole, 4- and 5-nitro-1,6-dihydro-1,6-dihydroxybenzo[1,2-d:3,4-d′]bistriazole and 4,7-dihydro-1,4,7-trihydroxy-1H-benzo-[1,2-d:3,4-d′:5,6-d″]tris[1,2,3]triazole

  • V. A. Samsonov
  • Yu. V. Gatilov
  • L. B. Volodarskii
Full Articles

Abstract

1,6-Dihydro-1,6-dihydroxybenzo[1,2-d:3,4-d′]bistriazole and 4- and 5-nitro-1,6-dihydro-1,6-dihydroxybenzo[1,2-d:3,4-d′]bistriazole were synthesized starting from 2,4-dinitrosore-sorcinol, whereas 4,7-dihydro-1,4,7-trihydroxy-1H-benzo[1,2-d:3,4-d′:5,6-d″]tris[1,2,3]-triazole was synthesized starting from phloroglucinol. The reaction of trinitrosophloroglucinol with hydrazine hydrate in acetic acid led to 2,4,6-tridiazocyclohexane-1,3,5-trione.

Key words

nitrosophenols 1-hydroxybenzotriazoles 2H-benzotriazole N-oxides dihydro-benzo[1,2-d:3,4-d′]bistriazoles benzotristriazoles diazoketones 

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Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  • V. A. Samsonov
    • 1
  • Yu. V. Gatilov
    • 1
  • L. B. Volodarskii
    • 1
  1. 1.N. N. Vorozhtsov Novosibirsk Institute of Organic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation

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