Abstract
Reactions of adamantan-1-ol with β-dicarbonyl compounds in 1,2-dichloroethane in the presence of In(OTf)3, Ga(OTf)3, Sc(OTf)3, or Cu(OTf)2 give the corresponding adamantylated derivatives in 45–93% yields.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1717–1719, September, 2012.
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Turmasova, A.A., Spesivaya, E.S., Konshina, D.N. et al. Adamantylation of β-dicarbonyl compounds. Russ Chem Bull 61, 1733–1735 (2012). https://doi.org/10.1007/s11172-012-0239-7
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DOI: https://doi.org/10.1007/s11172-012-0239-7