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2-Methyl-4,5-dihydrofurane hydroformylation

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Abstract

The synthesis of 2-methyl-3-formyl tetrahydrofurane as E-isomer via the hydroformylation of 2-methyl-4,5-dihydrofurane in the presence of complex phosphine-containing Rh-catalysts is performed. The dependence of the catalytic system type, pressure and temperature on the 2-methyl-4,5-dihydrofurane conversion and the selectivity of the formation of the aldehyde obtained is investigated.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry of Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    E. Yu. Vol’f, M. M. Vartanya & A. L. Lapidus

Authors
  1. E. Yu. Vol’f
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  2. M. M. Vartanya
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  3. A. L. Lapidus
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Corresponding author

Correspondence to E. Yu. Vol’f.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1241—1242, June, 2012.

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Vol’f, E.Y., Vartanya, M.M. & Lapidus, A.L. 2-Methyl-4,5-dihydrofurane hydroformylation. Russ Chem Bull 61, 1255–1256 (2012). https://doi.org/10.1007/s11172-012-0170-y

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  • DOI: https://doi.org/10.1007/s11172-012-0170-y

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