Skip to main content
SpringerLink
Log in

Decomposition of sodium hypochlorite in an aqueous solution in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) nitroxyl radical as a catalyst

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Nitroxyl radical TEMPO is found to catalyze the decomposition of sodium hypochlorite in an aqueous-alkali medium. The mechanism of NaOCl decomposition to form ClO· radical is proposed which involves protonated TEMPO, oxoammonium salt TEMPO+, and hydroxyl radical.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. E. J. de Nooy, A. C. Besemer, H. van Bekkum, Synthesis, 1996, 10, 1153.

    Article  Google Scholar 

  2. I. Yu. Ponedel’kina, E. A. Khaibrakhmanova, V. N. Odinokov, Usp. Khim., 2010, 79, 65 [Russ. Chem. Rev. (Engl. Transl.), 2010, 79, 63].

    Google Scholar 

  3. P. L. Bragd, H. van Bekkum, A. C. Besemer, Top. Catal., 2004, 27, 49.

    Article  CAS  Google Scholar 

  4. A. E. J. de Nooy, A. C. Besemer, H. van Bekkum, Carbohydr. Res., 1995, 269, 89.

    Article  Google Scholar 

  5. A. Jiang, E. Drouet, M. Milas, M. Rinaudo, Carbohydr. Res., 2000, 327, 455.

    Article  CAS  Google Scholar 

  6. Y. Kato, R. Matsuo, A. Isogai, Carbohydr. Polym., 2003, 69, 51.

    Google Scholar 

  7. M. H. Hashmi, A. A. Ayaz, A. Rashid, E. Ali, Anal. Chem., 1964, 36, 1379.

    Article  CAS  Google Scholar 

  8. D. M. Stanbury, Adv. Inorg. Chem., 1989, 33, 69.

    Article  CAS  Google Scholar 

  9. J. R. Fish, S. G. Swarts, M. D. Sevilla, T. Malinski, J. Phys. Chem., 1988, 92, 3745.

    Article  CAS  Google Scholar 

  10. L. C. Adam, I. Fabian, K. Suzuki, G. Gordon, Inorg. Chem., 1992, 31, 3534.

    Article  CAS  Google Scholar 

  11. L. C. Adam, G. Gordon, Inorg. Chem., 1999, 38, 1299.

    Article  CAS  Google Scholar 

  12. B. P. Nikol’skii, V. G. Krunchak, T. V. L’vova, V. V. Pal’chevskii, R. I. Sosnovskii, Dokl. Akad. Nauk, 1970, 191, 140 [Dokl. Chem. (Engl. Transl.), 1970].

    Google Scholar 

  13. B. P. Nikol’skii, V. G. Krunchak, V. V. Pal’chevskii, R. I. Sosnovskii, Dokl. Akad. Nauk, 1971, 197, 1324 [Dokl. Chem. (Engl. Transl.), 1971].

    Google Scholar 

  14. A. U. Khan, M. Kasha, Proc. Natl. Acad. Sci. USA, 1994, 91, 12362.

    Article  CAS  Google Scholar 

  15. J. A. Cella, J. A. Kelley, E. F. Kenehan, J. Org. Chem., 1975, 40, 1860.

    Article  CAS  Google Scholar 

  16. P. L. Anelli, C. Biffi, F. Montanari, S. Quici, J. Org. Chem., 1987, 52, 2559.

    Article  Google Scholar 

  17. T. Miyazawa, T. Endo, J. Org. Chem., 1985, 50, 3930.

    Article  CAS  Google Scholar 

  18. J. C. Morris, J. Phys. Chem., 1966, 70, 3798.

    Article  CAS  Google Scholar 

  19. J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett., 1996, 77, 3865.

    Article  CAS  Google Scholar 

  20. D. N. Laikov, Chem. Phys. Lett., 2005, 416, 116.

    Article  CAS  Google Scholar 

  21. D. N. Laikov, Yu. A. Ustynyuk, Izv. Akad. Nauk, Ser. Khim., 2005, 804 [Russ. Chem. Bull., Int. Ed., 2005, 54, 820].

    Google Scholar 

  22. D. Sh. Sabirov, R. G. Bulgakov, Comput. Theor. Chem., 2011, 963, 185.

    Article  CAS  Google Scholar 

  23. A. F. Shestakov, Ross. Khim. Zh., 2007, 51, 121 [Mendeleev Chem. J. (Engl. Transl.), 2007, 51].

    CAS  Google Scholar 

  24. F. Emmenegger, G. Gordon, Inorg. Chem., 1967, 6, 633.

    Article  CAS  Google Scholar 

  25. H. Taube, H. Dodgen, J. Am. Chem. Soc., 1949, 71, 3330.

    Article  CAS  Google Scholar 

  26. G. V. Buxton, M. S. Sumhani, J. Chem. Soc., Faraday Trans., 1972, 68, 947.

    CAS  Google Scholar 

  27. G. Porter, F. J. Wright, Disc. Faraday Soc., 1953, 14, 23.

    Article  Google Scholar 

  28. R. A. Cox, R. G. Derwent, A. E. Eggleton, H. J. Reid, J. Chem. Soc., Faraday Trans., 1979, 75, 1648.

    CAS  Google Scholar 

  29. R. A. Durie, D. A. Ramsay, Canad. J. Phys., 1958, 36, 35.

    Article  CAS  Google Scholar 

  30. E. G. Rozantsev, V. D. Sholle, Synthesis, 1971, 401.

    Google Scholar 

  31. M. Dagonneau, E. S. Kagan, V. I. Mikhailov, E. G. Rozantsev, V. D. Sholle, Synthesis, 1984, 895.

    Google Scholar 

  32. T. Endo, T. Miyazawa, S. Shiihashi, M. Okawara, J. Am. Chem. Soc., 1984, 106, 3877.

    Article  CAS  Google Scholar 

  33. Z. B. Alfassi, R. E. Huie, S. Mosseri, P. Neta, Radiat. Phys. Chem., 1988, 43, 85.

    Google Scholar 

  34. G. V. Buxton, M. S. Sumhani, J. Chem. Soc., Faraday Trans., 1972, 68, 958.

    Article  CAS  Google Scholar 

  35. J. A. Epstein, M. Lewin, J. Polym. Sci., 1962, 58, 991.

    Article  CAS  Google Scholar 

  36. O. Iguerb, S. Demoustier-Champagne, J. Marchand-Brynaert, D. Daoust, M. Sclavons, J. Devaux, J. Appl. Polym. Sci., 2006, 100, 1184.

    Article  CAS  Google Scholar 

  37. G. V. Buxton, F. S. Dainton, F. Wilkinson, Chem. Commun., 1966, 320.

    Google Scholar 

  38. L. Wang, D. W. Margerum, Inorg. Chem., 2002, 41, 6099.

    Article  CAS  Google Scholar 

  39. V. Csordas, B. Bubnis, I. Fabian, G. Gordon, Inorg. Chem., 2001, 40, 1833.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Bashkortostan, Russian Federation

    I. Yu. Ponedel’kina, E. A. Khaibrakhmanova, D. Sh. Sabirov & V. N. Odinokov

Authors
  1. I. Yu. Ponedel’kina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Khaibrakhmanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. Sh. Sabirov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Odinokov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. Yu. Ponedel’kina.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1164–1169, June, 2012.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ponedel’kina, I.Y., Khaibrakhmanova, E.A., Sabirov, D.S. et al. Decomposition of sodium hypochlorite in an aqueous solution in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) nitroxyl radical as a catalyst. Russ Chem Bull 61, 1176–1181 (2012). https://doi.org/10.1007/s11172-012-0160-0

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-012-0160-0

Key words

Search

Navigation