Russian Chemical Bulletin

, Volume 61, Issue 3, pp 662–664 | Cite as

Chemical equilibrium of esterification in AcOH-EtOH-H2O-EtOAc system at 293.15 K

  • A. M. Toikka
  • M. A. Trofimova
  • M. A. Toikka
Full Article


New experimental data on the chemical equilibrium of esterification in an acetic acid-ethanol-water-ethyl acetate system at 293.15 K and atmospheric pressure are presented.

Key words

chemical equilibrium esterification ethyl acetate 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    L. A. Serafimov, Yu. A. Pisarenko, N. N. Kulov, Chem. Eng. Sci., 1999, 54, 1383.CrossRefGoogle Scholar
  2. 2.
    Reactive Distillation: Status and Future Directions, Eds K. Sundmacher, A. Kienle, Weinheim, WILEY-VCH Verlag GmbH & Co. KGaA, 2003, 287 pp.Google Scholar
  3. 3.
    B. I. Gorovits, A. M. Toikka, Yu. A. Pisarenko, L. A. Serafimov, Teoret. Osnovy Khim. Tekhnol., 2006, 40, 258 [Theor. Found. Chem. Eng. (Engl. Transl.), 2006, 40, 239].Google Scholar
  4. 4.
    V. T. Zharov, Zh. Fiz. Khim., 1970, 44, 1967 [Russ. J. Phys. Chem. (Engl. Transl.), 1970, 44].Google Scholar
  5. 5.
    A. M. Toikka, M. A. Toikka, Yu. A. Pisarenko, L. A. Serafimov, Teoret. Osnovy Khim. Tekhnol., 2009, 43, 141 [Theor. Found. Chem. Eng. (Engl. Transl.), 2009, 43, 129].Google Scholar
  6. 6.
    Yu. A. Pisarenko, K. A. Kardona, L. A. Serafimov, Reaktsionno-rektifikatsionnye protsessy: dostizheniya v oblasti issledovaniya i prakticheskogo ispol’zovaniya [Reaction Rectification Processes: Achievements in the Area of Research and Practical Use], Luch, Moscow, 2001, 266 pp. (in Russian).Google Scholar
  7. 7.
    M. F. Doherty, M. F. Malone, Conceptual Design of Distillation Systems, McGraw-Hill, New York, 2001.Google Scholar
  8. 8.
    Yu. A. Pisarenko, L. A. Serafimov, N. N. Kulov, Teoret. Osnovy Khim. Tekhnol., 2009, 43, 491 [Theor. Found. Chem. Eng., 2009, 43 (Engl. Transl.)].Google Scholar
  9. 9.
    Yu. A. Pisarenko, Ph. D. (Techn.) Thesis, M. V. Lomonosov Institute of Fine Chemical Technology, Moscow, 1979 (in Russian).Google Scholar
  10. 10.
    N. Calvar, A. Dominguez, J. Tojo, Fluid Phase Equilib., 2005, 235, 215.CrossRefGoogle Scholar
  11. 11.
    Y. W. Kang, Y. Y. Lee, W. K. Lee, J. Chem. Eng. Jpn, 1992, 25, 649.CrossRefGoogle Scholar
  12. 12.
    E. A. Campanella, B. A. Mandagaran, Latin Amer. Appl. Research, 2003, 33, 223.Google Scholar
  13. 13.
    M. Frenkel, R. D. Chirico, V. Diky, A. F. Kazakov, C. D. Muzny, J. W. Magee, I. Abdulagatov, K. Kroenlein, Jeong Won Kang, NIST ThermoData Engine, NIST Standard Reference Database 103b-Pure Compounds, Binary Mixtures, and Chemical Reactions, version 5.0; Standard Reference Data Program, National Institute of Standards and Technology: Gaithersburg, MD, 2010.Google Scholar
  14. 14.
    A. M. Toikka, J. D. Jenkins, Chem. Eng. J., 2002, 89, 1.CrossRefGoogle Scholar
  15. 15.
    A. Toikka, M. Toikka, Pure Appl. Chem., 2009, 81, 1591.CrossRefGoogle Scholar
  16. 16.
    A. Toikka, M. Toikka, Fluid Phase Equilib., 2006, 250, 93.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  • A. M. Toikka
    • 1
  • M. A. Trofimova
    • 1
  • M. A. Toikka
    • 1
  1. 1.Chair of Chemical Thermodynamics and Kinetics, Chemical DepartmentSt. Petersburg State UniversitySt. PetersburgRussian Federation

Personalised recommendations