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3,4-Bis(α-nitroalkyl-ONN-azoxy)furazans and some of their derivatives

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Abstract

Reaction of pseudonitroles and their derivatives with diaminofurazan in the presence of dibromoisocyanuric acid (DBI) resulted in symmetrical 3,4-bis(-nitroalkyl-ONN-azoxy)-furazans or their derivatives. For the synthesis of bis(nitroalkyl-ONN-azoxy)furazans bearing various a-nitroalkyl-ONN-azoxy groups, the method based on the reaction of α-nitronitroso compounds with 3-amino-4-(nitroalkyl)-ONN-azoxy)furazans (in the presence of DBI) was developed. Synthetic procedures towards aforementioned compounds with nitromethyl-, dibromonitromethyl-, trinitromethyl-ONN-azoxy and other groups were described.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    O. A. Luk’yanov, G. V. Pokhvisneva, T. V. Ternikova & N. I. Shlykova

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  1. O. A. Luk’yanov
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  2. G. V. Pokhvisneva
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  3. T. V. Ternikova
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  4. N. I. Shlykova
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Corresponding author

Correspondence to O. A. Luk’yanov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 358–363, February, 2012.

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Luk’yanov, O.A., Pokhvisneva, G.V., Ternikova, T.V. et al. 3,4-Bis(α-nitroalkyl-ONN-azoxy)furazans and some of their derivatives. Russ Chem Bull 61, 360–365 (2012). https://doi.org/10.1007/s11172-012-0050-5

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  • DOI: https://doi.org/10.1007/s11172-012-0050-5

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