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Russian Chemical Bulletin

, Volume 60, Issue 12, pp 2510–2517 | Cite as

Reactions of dichloro-substituted iron(ii) clathrochelate with 1,4-dioxane radical derivatives: synthesis, structure, and spectral characteristics of the dioxane ring opening product in the ribbed fragment of the macrobicyclic ligand

  • M. A. Vershinin
  • A. B. Burdukov
  • Z. A. Starikova
  • V. V. Novikov
  • Ya. Z. Voloshin
Full Articles

Abstract

A free-radical substitution for the chlorine atoms with the 1,4-dioxan-2-yl fragment in the tris-dichloro-substituted dioximate iron(II) clathrochelate is accompanied by the oxidative dioxane ring opening as a side process. The compound obtained was characterized by elemental analysis data, 1D and 2D 1H and 13C{1H} NMR spectroscopy (in solution), MALDI TOF mass spectrometry, as well as by single-crystal X-ray diffraction.

Key words

clathrochelates reactions of coordinated ligands free-radical reactions 

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Copyright information

© Springer Science+Business Media New York 2011

Authors and Affiliations

  1. 1.A. V. Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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