Abstract
A free-radical substitution for the chlorine atoms with the 1,4-dioxan-2-yl fragment in the tris-dichloro-substituted dioximate iron(II) clathrochelate is accompanied by the oxidative dioxane ring opening as a side process. The compound obtained was characterized by elemental analysis data, 1D and 2D 1H and 13C{1H} NMR spectroscopy (in solution), MALDI TOF mass spectrometry, as well as by single-crystal X-ray diffraction.
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Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2461–2468, December, 2011.
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Vershinin, M.A., Burdukov, A.B., Starikova, Z.A. et al. Reactions of dichloro-substituted iron(ii) clathrochelate with 1,4-dioxane radical derivatives: synthesis, structure, and spectral characteristics of the dioxane ring opening product in the ribbed fragment of the macrobicyclic ligand. Russ Chem Bull 60, 2510–2517 (2011). https://doi.org/10.1007/s11172-011-0386-2
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DOI: https://doi.org/10.1007/s11172-011-0386-2