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Russian Chemical Bulletin

, Volume 60, Issue 10, pp 2110–2113 | Cite as

Cyclotrimerization of alkynes catalyzed by the naphthalene ruthenium complex [CpRu(C10H8)]+

  • D. S. Perekalin
  • E. A. Trifonova
  • P. V. Petrovskii
  • A. R. Kudinov
Brief Communications

Abstract

The naphthalene ruthenium complex [CpRu(C10H8)]+ (in the presence of Cl ions) catalyzes the cyclotrimerization of 2,2-dimethyl-5,5-dipropargyl-1,3-dioxane-4,6-dione with alkynes (acetylene, hex-1-yne, hex-3-yne, oct-1-yne, phenylacetylene, trimetylsilylacetylene, octa-1,7-diyne, pent-1-yn-5-ol, methyl propargyl ether, and propargyl acetate) giving tricyclic aromatic compounds in 55–85% yields.

Key words

alkynes diynes arenes cyclotrimerization ruthenium homogeneous catalysis 

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • D. S. Perekalin
    • 1
  • E. A. Trifonova
    • 1
  • P. V. Petrovskii
    • 1
  • A. R. Kudinov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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