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Cyclotrimerization of alkynes catalyzed by the naphthalene ruthenium complex [CpRu(C10H8)]+

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Abstract

The naphthalene ruthenium complex [CpRu(C10H8)]+ (in the presence of Cl− ions) catalyzes the cyclotrimerization of 2,2-dimethyl-5,5-dipropargyl-1,3-dioxane-4,6-dione with alkynes (acetylene, hex-1-yne, hex-3-yne, oct-1-yne, phenylacetylene, trimetylsilylacetylene, octa-1,7-diyne, pent-1-yn-5-ol, methyl propargyl ether, and propargyl acetate) giving tricyclic aromatic compounds in 55–85% yields.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. S. Perekalin, E. A. Trifonova, P. V. Petrovskii & A. R. Kudinov

Authors
  1. D. S. Perekalin
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  2. E. A. Trifonova
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  3. P. V. Petrovskii
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  4. A. R. Kudinov
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Corresponding author

Correspondence to A. R. Kudinov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2073–2076, October, 2011.

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Perekalin, D.S., Trifonova, E.A., Petrovskii, P.V. et al. Cyclotrimerization of alkynes catalyzed by the naphthalene ruthenium complex [CpRu(C10H8)]+ . Russ Chem Bull 60, 2110–2113 (2011). https://doi.org/10.1007/s11172-011-0324-3

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  • DOI: https://doi.org/10.1007/s11172-011-0324-3

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