Advertisement

Russian Chemical Bulletin

, Volume 60, Issue 9, pp 1940–1943 | Cite as

New polynitrogen hyperbranched polymers

  • G. V. Malkov
  • A. V. Shastin
  • Ya. I. Estrin
  • E. R. Badamshina
  • Yu. M. Mikhailov
Full Articles

Abstract

A method for the preparation of new representatives of polynitrogen hyperbranched polymers of heterocyclic series was developed involving polymerization of monomeric 2,4-diazido-6-propynyloxy-1,3,5-triazine by 1,3-dipolar cycloaddition. Kinetics of polymerization of diazidoacetylene monomer was compared with the kinetic data of polymerization of its closest analog, 2-azido-4,6-bis(propynyloxy)-1,3,5-triazine monomer. Properties of hyperbranched poly(1,2,3-triazole-1,3,5-triazine)s with terminal azide groups and terminal triple bonds were compared, as well.

Key words

hyperbranched polymers 1,3-dipolar cycloaddition azides alkynes 1,2,3-triazoles 1,3,5-triazines kinetics size exclusion chromatography light scattering detector (SEC-MALLS) 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    D. A. Tomalia, A. M. Naylor, W. A. Goddart, Angew. Chem., Int. Ed. Engl., 1990, 29, 138.CrossRefGoogle Scholar
  2. 2.
    G. R. Newkome, Advances in Dendritic Macromolecules, Vol. I, JAI Press, Greenwich, 1994.Google Scholar
  3. 3.
    I. P. Beletskaya, A. V. Chuchuryukin, Usp. Khim., 2000, 69, 699 [Russ. Chem. Rev. (Engl. Transl.), 2000, 69, 639].Google Scholar
  4. 4.
    C. Gao, D. Y. Yan, Prog. Polym. Sci., 2004, 29, 183.CrossRefGoogle Scholar
  5. 5.
    L. M. Bronshtein, S. N. Sidorov, P. M. Valetskii, Usp. Khim., 2004, 73, 542 [Russ. Chem. Rev. (Engl. Transl.), 2004, 73, 501].Google Scholar
  6. 6.
    P. Florian, K. K. Jena, S. Allauddin, R. Narayan, K. V. S. N. Raju, Ind. Eng. Chem. Res., 2010, 49, 4517.CrossRefGoogle Scholar
  7. 7.
    D. Astruc, E. Boisselier, C. Ornelas, Chem. Rev., 2010, 110, 1857.CrossRefGoogle Scholar
  8. 8.
    A. Ghosh, S. Banerjee, H. Komber, A. Lederer, L. Hussler, B. Voit, Macromolecules, 2010, 43, 2846.CrossRefGoogle Scholar
  9. 9.
    A. J. Scheel, H. Komber, B. I. Voit, Macromol. Chem., Rapid Commun., 2004, 25, 1175.CrossRefGoogle Scholar
  10. 10.
    M. Smet, K. Metten, W. Dehaen, Collect. Czech. Chem. Commun., 2004, 69, 1097.CrossRefGoogle Scholar
  11. 11.
    B. Voit, S. Fleischmann, H. Komber, A. Scheel, K. Stumpe, Macromol. Symp., 2007, 254, 16.Google Scholar
  12. 12.
    G. V. Malkov, V. P. Lodygina, A. V. Shastin, Ya. I. Estrin, E. R. Badamshina, Yu. M. Mikhailov, Vysokomolekulyar. Soedin., Ser. B, 2007, 49, 2211 [Polym. Sci., Ser. B (Engl. Transl.), 2007, 49, 301].Google Scholar
  13. 13.
    G. V. Malkov, A. V. Shastin, Y. I. Estrin, E. R. Badamshina, Y. M. Mikhailov, Propellants, Explosives, Pyrotechnics, 2008, 33, 431.CrossRefGoogle Scholar
  14. 14.
    G. V. Malkov, A. V. Shastin, Y. I. Estrin, E. R. Badamshina, Y. M. Mikhailov, Macromol. Symp., 2010, 296, 107.CrossRefGoogle Scholar
  15. 15.
    US Pat. 2911337 (A); Chem. Abstr., 1960, 60, 3840.Google Scholar
  16. 16.
    NL Pat. 6413689; Chem. Abstr., 1966, 64, 741h.Google Scholar

Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • G. V. Malkov
    • 1
  • A. V. Shastin
    • 1
  • Ya. I. Estrin
    • 1
  • E. R. Badamshina
    • 1
  • Yu. M. Mikhailov
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation

Personalised recommendations