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Russian Chemical Bulletin

, Volume 60, Issue 9, pp 1814–1819 | Cite as

Adsorption of isomeric aryl- and diadamantane molecules on the surface of graphitized thermal carbon black

  • S. N. Yashkin
  • D. A. Svetlov
  • V. S. Sarkisova
Full Articles

Abstract

The thermodynamic characteristics of adsorption of isomeric molecules of 1,1′-, 1,2′-, and 2,2′-diadamantanes, 1- and 2-phenyladamantanes, and 1-cyclohexyladamantane on the surface of graphitized thermal carbon black (GTC) were experimentally determined. The influence of the molecular structure of adsorbates on their adsorption on the basis face of graphite was considered. A high selectivity of the GTC surface for the gas chromatographic separation of mixtures of the considered structural isomers was shown.

Key words

aryladamantanes diadamantanes graphitized thermal carbon black Henry’s constant heat of adsorption entropy of adsorption model of dimeric ideal gas 

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • S. N. Yashkin
    • 1
  • D. A. Svetlov
    • 1
  • V. S. Sarkisova
    • 1
  1. 1.Samara State Technical UniversitySamaraRussian Federation

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