Russian Chemical Bulletin

, Volume 60, Issue 8, pp 1762–1765 | Cite as

Cage-like manganesephenylsiloxane with an unusual structure

  • A. N. Bilyachenko
  • M. S. Dronova
  • A. A. Korlyukov
  • M. M. Levitsky
  • M. Yu. Antipin
  • B. G. Zavin
Brief Communications


A polyhedral (manganese,sodium)phenylsiloxane of the composition (C6H5SiO1,5)20(MnO)8(NaO0,5)12·2NaOH·15C2H5OH·11 H2O (the molecular formula is C150H214Mn8Na14O72Si20) was synthesized. This compound possesses the earlier undescribed shape of the cage and a rare combination of silanolate anions Si-O and metalloxide fragments Mn-O-Mn in one structure. The coordination sphere of Mn ions is filled with silanolate anions, the O atoms in the fragments Mn-O-Si, Mn-O-Mn, and encapsulated molecules of water. The molecules of solvate ethanol are coordinated exclusively with Na+ cations and are not involved into coordination sphere of MnII ions.

Key words

cage-like metallasiloxanes X-ray crystallography 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    V. Lorenz, A. Fischer, S. Gießmann, J. W. Gilje, Y. Gun’ko, K. Jacob, F. T. Edelmann, Coord. Chem. Rev., 2000, 206–207, 321.CrossRefGoogle Scholar
  2. 2.
    H. W. Roesky, G. Anantharaman, V. Chandrasekhar, V. Jancik, S. Singh, Chem. Eur. J., 2004, 10, 4106.CrossRefGoogle Scholar
  3. 3.
    M. M. Levitsky, B. G. Zavin, A. N. Bilyachenko, Usp. Khim., 2007, 76, 907 [Russ. Chem. Rev. (Engl. Transl.), 2007, 76].Google Scholar
  4. 4.
    R. W. J. M. Hanssen, R. A. van Santen, H. C. L. Abbenhuis, Eur. J. Inorg. Chem., 2004, 675.Google Scholar
  5. 5.
    M. M. Levitsky, V. V. Smirnov, B. G. Zavin, A. N. Bilyachenko, A. Yu. Rabkina, Kinet. Katal., 2009, 50, 512 [Kinet. Catal. (Engl. Transl.), 2009, 50].Google Scholar
  6. 6.
    M. M. Levitsky, O. I. Shchegolikhina, A. A. Zhdanov, V. A. Igonin, Yu. E. Ovchinnikov, V. E. Shklover, Yu. T. Struchkov, J. Organomet. Chem., 1991, 401, 199.CrossRefGoogle Scholar
  7. 7.
    U. N. Nehete, H. W. Roesky, H. Zhu, Sh. Nembenna, H. G. Schmidt, M. Noltemeyer, D. Bogdanov, K. Samwer, Inorg. Chem., 2005, 44, 7243.CrossRefGoogle Scholar
  8. 8.
    U. N. Nehete, V. Chandrasekhar, V. Jancik, H. W. Roesky, R. Herbst-Irmer, Organometallics, 2004, 23, 5372.CrossRefGoogle Scholar
  9. 9.
    U. N. Nehete, V. Chandrasekhar, G. Anantharaman, H. W. Roesky, D. Vidovic, J. Magull, Angew. Chem., Int. Ed., 2004, 43, 3842.CrossRefGoogle Scholar
  10. 10.
    V. Lorenz, S. Blaurock, H. Görls, F. T. Edelmann, Organometallics, 2006, 25, 5922.CrossRefGoogle Scholar
  11. 11.
    H. M. Lindemann, M. Schneider, B. Neumann, H.-G. Stammler, A. Stammler, P. Jutzi, Organometallics, 2002, 21, 3009.CrossRefGoogle Scholar
  12. 12.
    J.-O. Nolte, M. Schneider, B. Neumann, H.-G. Stammler, P. Jutzi, Organometallics, 2003, 22, 1010.CrossRefGoogle Scholar
  13. 13.
    A. Voigt, R. Murugavel, M. L. Montero, H. Wessel, F.-Q. Liu, H. W. Roesky, I. Usyn, T. Albers, E. Parisini, Angew. Chem., Int. Ed. (Engl.), 1997, 36, 1001.CrossRefGoogle Scholar
  14. 14.
    F. T. Edelmann, S. Griesmann, A. Fischer, J. Organometallic Chem., 2001, 620, 80.CrossRefGoogle Scholar
  15. 15.
    A. N. Bilyachenko, A. A. Korlyukov, M. M. Levitsky, M. Yu. Antipin, B. G. Zavin, Izv. Akad. Nauk, Ser. Khim., 2007, 522 [Russ. Chem. Bull., Int. Ed., 2007, 56, 543].Google Scholar
  16. 16.
    V. A. Igonin, O. I. Shchegolikhina, S. V. Lindeman, M. M. Levitsky, Yu. T. Struchkov, A. A. Zhdanov, J. Organomet. Chem., 1992, 423, 351.CrossRefGoogle Scholar
  17. 17.
    V. Riollet, E. A. Quadrelli, C. Copéret, J.-M. Basset, R. A. Andersen, K. Köhler, R.-M. Böttcher, E. Herdtweck, Chem. Eur. J., 2005, 11, 7358.CrossRefGoogle Scholar
  18. 18.
    V. Lorenz, S. Blaurock, F. T. Edelmann, Z. Anorg. Allg. Chem., 2008, 634, 2819.CrossRefGoogle Scholar
  19. 19.
    SHELXTL, Version 5.10, Bruker-AXS Inc., Madison, WI-53719, USA, 1998.Google Scholar

Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • A. N. Bilyachenko
    • 1
  • M. S. Dronova
    • 1
  • A. A. Korlyukov
    • 1
  • M. M. Levitsky
    • 1
  • M. Yu. Antipin
    • 1
  • B. G. Zavin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations