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Russian Chemical Bulletin

, Volume 60, Issue 8, pp 1712–1718 | Cite as

Synthesis of 3-nitramino-4-(1H-1,2,3-triazol-1-yl)-1,2,5-oxadiazoles and their salts

  • V. Yu. Rozhkov
  • L. V. Batog
  • M. I. Struchkova
Full Articles

Abstact

Nitration of 3-amino-4-(1H-1,2,3-triazol-1-yl)-1,2,5-oxadiazoles (3-amino-4-triazolylfurazans) with a mixture of NaNO3 and conc. H2SO4 gave for the first time triazolylfurazans with a primary nitramino group attached to the furazan ring. If the starting amino(triazolyl)-furazan contains an aromatic substituent, the latter also undergoes nitration under the conditions studied. Some of these nitramines were converted into salts (K, Na, and NH4).

Key words

amino(1,2,3-triazol-1-yl)furazans nitramino(1,2,3-triazol-1-yl)furazans 4-amino-3-azidofurazan 1,3-dicarbonyl compounds 1,3-cycloaddition nitration hydrolysis decarboxylation nitramino(triazolyl)furazan salts NMR spectroscopy 

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • V. Yu. Rozhkov
    • 1
  • L. V. Batog
    • 1
  • M. I. Struchkova
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation

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