Russian Chemical Bulletin

, Volume 60, Issue 8, pp 1657–1662 | Cite as

Effect of different types of radiation on the composition of poly(phosphazene) surface

  • A. V. Naumkin
  • I. O. Volkov
  • A. A. Lapchenko
  • A. S. Lapchenko
  • D. R. Tur
Full Articles


Changes in the composition of poly[bis(trifluoroethoxy)phosphazene] surface irradiated at λ = 6700 Å (a laser), at λ = 9.89 Å (1253.6 eV, X-ray Mg-Kα radiation), and at 4720 Å (a light emitting diode, (LED) for medical applications) were studied in situ by X-ray photoelectron spectroscopy. Both quantitative and qualitative changes in the surface composition compared to routine measurements of the polymer spectra are observed during an analysis of the surface upon long-term X-ray irradiation or with an increase in the X-ray radiation source power. These are the changes in the concentrations of elements and the appearance of additional states of carbon, oxygen, and nitrogen atoms. The composition of the surface irradiated with the laser and LED remains unchanged.

Key words

poly(phosphazene) X-ray photoelectron spectroscopy X-ray radiation polymer degradation surface composition activation energy 


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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • A. V. Naumkin
    • 1
  • I. O. Volkov
    • 1
  • A. A. Lapchenko
    • 2
  • A. S. Lapchenko
    • 2
  • D. R. Tur
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.Federal Agency on Health Protection and Social DevelopmentRussian State Medical UniversityMoscowRussian Federation

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