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Russian Chemical Bulletin

, Volume 60, Issue 7, pp 1440–1447 | Cite as

Models for unimolecular reactions in the solid phase and stability prediction of energetic compounds in the condensed state

  • G. B. Manelis
  • G. M. Nazin
  • V. G. Prokudin
Full Articles

Abstract

The results of analysis and refinement of phenomenological models for unimolecular reactions proceeding homogeneously in the bulk of undistorted crystal lattice or localized on the lattice defects are presented. It is shown that, within the framework of these models, the ratio of the rate constants for reactions in the liquid and solid phases, K = k l/k s, can be calculated with satisfactory accuracy and thus the known k l values can be used to predict the rate constant k s characterizing the stability of the materials.

Key words

unimolecular reactions solid phase additional volume model 

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation

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