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Dye J-aggregate—semiconductor nanocrystal hybrid nanostructures in reverse micelles: an experimental study

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Abstract

Reverse micelle solutions can be used for the assembly of hybrid nanostructures of the composition dye monomer—Ag2S nanocrystal, dye J-aggregate—CuI nanocrystal, and dye J-aggregate—PbI2 nanocrystal. The assembly is effected by means of adsorption of the dye (3,3′-di-(γ-sulfopropyl)-4,5,4′,5′-dibenzo-9-ethylthiacarbocyanine betaine pyridinium salt) onto the nanocrystal surface. Factors responsible for the dye adsorption onto semiconductor nanocrystals in reverse micelle solutions are analyzed. It is suggested that adsorption can be the outcome of forces induced by both van der Waals and chemical interactions. The surfactants used for stabilization of reverse micelle solutions also influence the assembly of the hybrid nanostructures.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    L. M. Nikolenko, S. B. Brichkin & V. F. Razumov

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  1. L. M. Nikolenko
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  2. S. B. Brichkin
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  3. V. F. Razumov
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Correspondence to L. M. Nikolenko.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1170–1176, June, 2011.

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Nikolenko, L.M., Brichkin, S.B. & Razumov, V.F. Dye J-aggregate—semiconductor nanocrystal hybrid nanostructures in reverse micelles: an experimental study. Russ Chem Bull 60, 1196–1202 (2011). https://doi.org/10.1007/s11172-011-0188-6

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  • DOI: https://doi.org/10.1007/s11172-011-0188-6

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