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The rate of cyclization of 2′- and 4′-substituted diphenylamine-2-carboxylic acids in sulfuric acid as a function of the electronic properties of substituents

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Abstract

The kinetic regularities of cyclization of 2′- and 4′-substituted diphenylamine-2-carboxylic acids in sulfuric acid were determined. The rate of cyclization of diphenylamine-2-carboxylic acids is linearly dependent on the nature of substituents in the meta-position relative to the reaction site in accordance with the two-parameter Hammett equation.

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Authors and Affiliations

  1. South-West State University, 94 ul. 50 let Oktyabrya, 305040, Kursk, Russian Federation

    N. A. Pelevin, Yu. D. Markovich, T. N. Kudryavtseva & M. I. Brylev

  2. High-Tech Laboratory Ltd., 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    G. V. Nazarov & S. E. Galan

Authors
  1. N. A. Pelevin
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  2. Yu. D. Markovich
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  3. G. V. Nazarov
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  4. S. E. Galan
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  5. T. N. Kudryavtseva
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  6. M. I. Brylev
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Correspondence to N. A. Pelevin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 577—579, March, 2011.

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Pelevin, N.A., Markovich, Y.D., Nazarov, G.V. et al. The rate of cyclization of 2′- and 4′-substituted diphenylamine-2-carboxylic acids in sulfuric acid as a function of the electronic properties of substituents. Russ Chem Bull 60, 590–592 (2011). https://doi.org/10.1007/s11172-011-0092-0

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  • DOI: https://doi.org/10.1007/s11172-011-0092-0

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