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Synthesis of azacrown ethers and benzocryptands by macrocyclization of podands at high concentrations of reactants

  • M. S. Oshchepkov
  • V. P. Perevalov
  • L. G. Kuzmina
  • A. V. Anisimov
  • O. A. Fedorova
Full Articles

Abstract

The reactions of 1,2-bis(2-Y-ethoxy)benzenes, N,N-bis(2-Y-ethyl)-N-phenylamines, or 2,6-bis(Y-methyl)pyridines (Y = I, Br, or OTs) with α,ω-polyoxaalkanediamines or diazacrown ethers in the presence or absence of alkali carbonates in a concentrated acetonitrile solution of the reactants afforded the corresponding azacrown ethers or cryptands in high yields.

Key words

macrocyclization of azapolyethers diamines alkali carbonates azacrown ethers cryptands crown compounds 

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • M. S. Oshchepkov
    • 1
  • V. P. Perevalov
    • 1
  • L. G. Kuzmina
    • 2
  • A. V. Anisimov
    • 3
  • O. A. Fedorova
    • 1
    • 3
  1. 1.D. I. Mendeleev University of Chemical Technology of RussiaMoscowRussian Federation
  2. 2.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussian Federation
  3. 3.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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