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Russian Chemical Bulletin

, Volume 60, Issue 1, pp 89–98 | Cite as

Heteroassociates of singly- and doubly-charged anions of alizarin red S with the pinacyanol cation

  • S. A. Shapovalov
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Abstract

The formation of heteroassociates of singly- and doubly-charged anions of alizarin red S with the cation of the cyanine dye pinacyanol in an aqueous solution was considered. The most probable structure of the heteroassociates was proposed on the basis of the data of spectrophotometry and theoretical calculations (quantum chemical methods of determination of the geometry of the structures and the enthalpy of formation). The destructive effect of the ionic surfactants on the heteroassociates was established, and the kinetics of their destruction was studied.

Key words

dye absorption spectra association enthalpy of formation semiempirical methods alizarin red S pinacyanol solution ionic surfactants kinetics 

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  1. 1.V. N. Karazin Khar’kov National UniversityKhar’kovUkraine

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