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New molecular magnetic metals: κ-(BDH-TTP)4CuCl4·(H2O) n and κ-(BDH-TTP)2[CuCl4]0.67·(H2O)0.33 (BDH-TTP is 2,5-bis(1,3-dithiolan-2-ylidene)-1,3,4,6-tetrathiapentalene)

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Abstract

New radical cation salts based on 2,5-bis(1,3-dithiolan-2-ylidene)-1,3,4,6-tetrathiapentalene (BDH-TTP), viz., κ-(BDH-TTP)4CuCl4·(H2O) n (1) and κ-(BDH-TTP)2[CuCl4]0.67· ·(H2O)0.33 (2), were synthesized and structurally characterized. Single crystals were prepared by the electrochemical oxidation of BDH-TTP under galvanostatic conditions. The X-ray diffraction study showed that the salts have layered structures characterized by the presence of κ-type BDH-TTP conducting layers. These layers alternate with the complex anions composed of [CuCl4]2− units and water molecules. Both salts exhibit the temperature dependence of the metallic conductivity down to 4.2 K. Spin-spin antiferromagnetic correlations in the Cu2+ subsystem were observed in the crystals of 2.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    N. D. Kushch, A. V. Kazakova, L. I. Buravov & E. B. Yagubskii

  2. Institute of Solid State Physics, Russian Academy of Sciences, ul. Institutskaya, 142432, Chernogolovka, Moscow Region, Russian Federation

    S. V. Simonov, L. V. Zorina, S. S. Khasanov & R. P. Shibaeva

  3. Department of Material Science, Graduate School of Material Science, University of Hyogo, 3-2-1 Kyoto, Kamigori-cho Ako-gun, Hyogo, 678-1297, Japan

    J. Yamada & M. Umemiya

Authors
  1. N. D. Kushch
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  2. A. V. Kazakova
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  3. L. I. Buravov
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  4. E. B. Yagubskii
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  5. S. V. Simonov
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  6. L. V. Zorina
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  7. S. S. Khasanov
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  8. R. P. Shibaeva
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  9. J. Yamada
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  10. M. Umemiya
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Corresponding authors

Correspondence to N. D. Kushch or E. B. Yagubskii.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1683–1688, September, 2010.

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Kushch, N.D., Kazakova, A.V., Buravov, L.I. et al. New molecular magnetic metals: κ-(BDH-TTP)4CuCl4·(H2O) n and κ-(BDH-TTP)2[CuCl4]0.67·(H2O)0.33 (BDH-TTP is 2,5-bis(1,3-dithiolan-2-ylidene)-1,3,4,6-tetrathiapentalene). Russ Chem Bull 59, 1729–1734 (2010). https://doi.org/10.1007/s11172-010-0304-z

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  • DOI: https://doi.org/10.1007/s11172-010-0304-z

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