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Russian Chemical Bulletin

, Volume 59, Issue 8, pp 1665–1667 | Cite as

Carboranyl phosphites: the electronic effect in the Suzuki- Miyaura reaction

  • S. E. Lyubimov
  • T. A. Verbitskaya
  • E. G. Rys
  • P. V. Petrovskii
  • M. M. Ilín
  • V. A. Davankov
  • V. N. Kalinin
Brief Communications

Abstract

Isomeric carborane-containing phosphite ligands possessing different electronic properties have been synthesized. Their use in the Pd-catalyzed Suzuki-Miyaura reaction involving activated aryl bromides showed that phosphite with 9-o-carborane substituent has proved more efficient, with carboranyl phosphite having 1-m- carborane fragment being more efficient in the reactions with nonactivated aryl bromides.

Key words carboranes cross-coupling phenylboronic acid aryl halides phosphites 

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Copyright information

© Springer Science+Business Media, Inc.  2010

Authors and Affiliations

  • S. E. Lyubimov
    • 1
  • T. A. Verbitskaya
    • 1
  • E. G. Rys
    • 1
  • P. V. Petrovskii
    • 1
  • M. M. Ilín
    • 1
  • V. A. Davankov
    • 1
  • V. N. Kalinin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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