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Russian Chemical Bulletin

, Volume 59, Issue 7, pp 1317–1326 | Cite as

Heteroassociation of the bromine-containing anions of sulfophthaleins in aqueous solution

  • S. A. Shapovalov
  • Ya. S. Kiseleva
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  • 54 Downloads

Abstract

The ability of bromine-containing anions of sulfophthalein dyes, such as bromophenol blue (BPB), bromocresol green (BCG), bromocresol purple (BCP), bromothymol blue (BTB), as well as non-substituted phenol red (PhR), to form heteroassociates in aqueous solution was investigated. Singly and doubly charged anions BPB, BCG, BCP, BTB, and PhR (HAn-, An2-) are capable of forming stable heteroassociates of composition Ct+•HAn- and (Ct+)2•An2- with cationic polymethine dyes (Ct+), such as pinacyanol and quinaldine red. The enthalpies of formation of the dye ions and heteroassociates were calculated by semiempirical methods, and the most probable structure of heteroassociates was determined.

Key words sulfophthaleins heteroassociation spectrophotometry aqueous solution dye constant of association enthalpy of formation 

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Copyright information

© Springer Science+Business Media, Inc.  2010

Authors and Affiliations

  1. 1.V. N. Karazin Kharkov National UniversityKharkovUkraine

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