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Russian Chemical Bulletin

, Volume 59, Issue 2, pp 476–479 | Cite as

Synthesis, structure, luminescence and magnetic properties of the coordination polymer {[Eu(H2O)5][Mo(CN)8]} containing bridging cyanide ligands

  • E. N. Chelebaeva
  • A. A. Trifonov
  • J. E. Larionova
  • Y. Guari
  • R. A. Sa Fereira
  • L. D. Carlos
  • F. A. Almeida Paz
  • Ch. Guérin
Brief Communications

Abstract

The reaction of [Eu(H2O)6](NO3)3 and [N(C4H9)4]3[Mo(CN)8]·2H2O afforded a new two-dimensional coordination polymer {[Eu(H2O)5[Mo(CN)8]} (1) in which the europium and molybdenum atoms are bound through the bridging CN groups. The luminescence and magnetic properties of complex 1 were studied in a wide temperature range.

Key words

lanthanides coordination polymers polycyanometallates luminescence magnetism 

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Copyright information

© Springer Science+Business Media, Inc.  2010

Authors and Affiliations

  • E. N. Chelebaeva
    • 1
  • A. A. Trifonov
    • 1
  • J. E. Larionova
    • 2
  • Y. Guari
    • 2
  • R. A. Sa Fereira
    • 3
  • L. D. Carlos
    • 3
  • F. A. Almeida Paz
    • 4
  • Ch. Guérin
    • 2
  1. 1.G. A. Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussian Federation
  2. 2.Laboratory of Molecular Chemistry and Solid State Organization, Charles Gerhardt InstituteUniversity of Montpellier-IIMontpellier cedex 5France
  3. 3.Department of PhysicsUniversity of AveiroAveiroPortugal
  4. 4.Department of Chemistry and CICECOUniversity of AveiroAveiroPortugal

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