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Russian Chemical Bulletin

, Volume 58, Issue 12, pp 2494–2498 | Cite as

Sulfur-containing heterocycles 14. New synthesis of cyclic anhydrides of 3-sulfinocarboxylic acids

  • T. P. Vasil’eva
  • G. T. Shchetnikov
  • S. N. Osipov
Full Articles

Abstract

3-Chlorosulfinylalkanoyl chlorides undergo cyclization into the corresponding five-membered mixed anhydrides (1,2-oxathiolan-5-one 2-oxides) under the action of sodium or mercury acetates. 2-Chlorosulfinylbenzoyl chloride gives 3H-2,1-benzoxathiol-3-one 1-oxide in high yield.

Key words

3H-2,1-benzoxathiol-3-one 1-oxide 1,2-oxathiolan-5-one 2-oxides anhydrides sulfinic acids 2-chlorosulfinylbenzoyl chloride cyclization ring-chain tautomerism 

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Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  • T. P. Vasil’eva
    • 1
  • G. T. Shchetnikov
    • 1
  • S. N. Osipov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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