Russian Chemical Bulletin

, Volume 58, Issue 11, pp 2246–2249 | Cite as

Copper(II) camphorates with tunable pore size in metal-organic frameworks

  • D. N. Dybtsev
  • M. P. Yutkin
  • V. P. Fedin
Full Articles


Three new homochiral metal-organic coordination polymers [Cu2camph2dabco] · DMF•2H2O, [Cu2camph2bipy] · 3DMF•2H2O, and [Cu2camph2bpe] · 4DMF•2H2O (H2camph is (+)-camphoric acid, bipy is 4,4’-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.

Key words

copper(II) complexes coordination polymers frameworks chiral structures powder X-ray diffraction 


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Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  1. 1.A. V. Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation
  2. 2.Novosibirsk State UniversityNovosibirskRussian Federation

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