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Russian Chemical Bulletin

, Volume 58, Issue 11, pp 2246–2249 | Cite as

Copper(II) camphorates with tunable pore size in metal-organic frameworks

  • D. N. Dybtsev
  • M. P. Yutkin
  • V. P. Fedin
Full Articles

Abstract

Three new homochiral metal-organic coordination polymers [Cu2camph2dabco] · DMF•2H2O, [Cu2camph2bipy] · 3DMF•2H2O, and [Cu2camph2bpe] · 4DMF•2H2O (H2camph is (+)-camphoric acid, bipy is 4,4’-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.

Key words

copper(II) complexes coordination polymers frameworks chiral structures powder X-ray diffraction 

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References

  1. 1.
    O. M. Yaghi, H. Li, C. Davis, D. Richardson, T. L. Groy, Acc. Chem. Res., 1998, 31, 474.CrossRefGoogle Scholar
  2. 2.
    R. Robson, J. Chem. Soc., Dalton Trans., 2000, 3735.Google Scholar
  3. 3.
    B. F. Hoskins, R. Robson, J. Am. Chem. Soc., 1990, 112, 1546.CrossRefGoogle Scholar
  4. 4.
    O. M. Yaghi, M. O’Keeffe, N. W. Ockwing, H. K. Chae, M. Eddaoudi, J. Kim, Nature, 2003, 423, 705.CrossRefGoogle Scholar
  5. 5.
    C. Janiak, J. Chem. Soc., Dalton Trans., 2003, 2781.Google Scholar
  6. 6.
    S. Kitagawa, R. Kitaura, S.-i. Noro, Angew. Chem., Int. Ed., 2004, 43, 2334.CrossRefGoogle Scholar
  7. 7.
    B. Kesanli, W. Lin, Coord. Chem. Rew., 2003, 246, 305.CrossRefGoogle Scholar
  8. 8.
    D. N. Dybtsev, A. L. Nuzhdin, H. Chun, K. P. Bryliakov, E. P. Talsi, V. P. Fedin, K. Kim, Angew. Chem., Int. Ed., 2006, 45, 916.CrossRefGoogle Scholar
  9. 9.
    A. L. Nuzhdin, D. N. Dybtsev, K. P. Bryliakov, E. P. Talsi, V. P. Fedin, J. Am. Chem. Soc., 2007, 129, 12958.CrossRefGoogle Scholar
  10. 10.
    G. Li, W. Yu, Y. Cui, J. Am. Chem. Soc., 2008, 130, 4582.CrossRefGoogle Scholar
  11. 11.
    R.-G. Xiong, X.-Z. You, B. F. Abrahams, Z. Xue, C.-M. Che, Angew. Chem., Int. Ed., 2001, 40, 4422.CrossRefGoogle Scholar
  12. 12.
    J. S. Seo, D. Wand, H. Lee, S. I. Jun, J. Oh, Y. Jeon, K. Kim, Nature, 2000, 404, 982.CrossRefGoogle Scholar
  13. 13.
    M. J. Ingleson, J. P. Barrio, J. Bacsa, C. Dickinson, H. Park, M. J. Rosseinsky, Chem. Commun., 2008, 1287.Google Scholar
  14. 14.
    C.-D. Wu, A. Hu, L. Zhang, W. Lin, J. Am. Chem. Soc., 2005, 127, 8940.CrossRefGoogle Scholar
  15. 15.
    S.-H. Cho, B. Ma, S. T. Nguyen, J. T. Hupp, T. E. Albrecht-Schmitt, Chem. Commun., 2006, 2563.Google Scholar
  16. 16.
    D. N. Dybtsev, M. P. Yutkin, E. V. Peresypkina, A. V. Virovets, C. Serre, G. Férey, V. P. Fedin, Inorg. Chem., 2007, 17, 6843.CrossRefGoogle Scholar
  17. 17.
    P. van der Sluis, A. L. Spek, Acta Crystallogr., 1990, 46, 194.CrossRefGoogle Scholar
  18. 18.
    J. P. Barrio, J.-N. Rebilly, B. Carter, D. Bradshaw, J. Bacsa, A. Y. Ganin, H. Park, A. Trewin, R. Vaidhyanathan, A. I. Cooper, J. E. Warren, M. J. Rosseinsky, Chem. Eur. J., 2008, 14, 4521.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  1. 1.A. V. Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation
  2. 2.Novosibirsk State UniversityNovosibirskRussian Federation

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