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Copper(II) camphorates with tunable pore size in metal-organic frameworks

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Abstract

Three new homochiral metal-organic coordination polymers [Cu2camph2dabco] · DMF•2H2O, [Cu2camph2bipy] · 3DMF•2H2O, and [Cu2camph2bpe] · 4DMF•2H2O (H2camph is (+)-camphoric acid, bipy is 4,4’-bipyridyl, bpe is trans-bis(4-pyridyl)ethylene) were synthesized by heating copper(II) nitrate, (+)-camphoric acid, and N-donor ligands of different length (dabco, bipy, bpe) in DMF and characterized by powder X-ray diffraction, IR spectroscopy, and TGA. The obtained compounds are isostructural with the previously reported porous zinc(II) camphorates.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    D. N. Dybtsev, M. P. Yutkin & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    D. N. Dybtsev & V. P. Fedin

Authors
  1. D. N. Dybtsev
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  2. M. P. Yutkin
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  3. V. P. Fedin
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Correspondence to V. P. Fedin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2179–2182, November, 2009.

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Dybtsev, D.N., Yutkin, M.P. & Fedin, V.P. Copper(II) camphorates with tunable pore size in metal-organic frameworks. Russ Chem Bull 58, 2246–2249 (2009). https://doi.org/10.1007/s11172-009-0313-y

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  • DOI: https://doi.org/10.1007/s11172-009-0313-y

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