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Russian Chemical Bulletin

, Volume 58, Issue 8, pp 1650–1653 | Cite as

Effect of the solvent on the radius of exchange interactions of d0-metal complexes with cyclopentadiene

  • G. V. Loukova
  • V. P. Vasiliev
  • V. A. Smirnov
Full Articles
  • 39 Downloads

Abstract

The effect of solvent on the efficiency of exchange-resonant energy transfer from d0-organometallic π-complexes to nonphosphorescent cyclopentadiene in glassy organic solvents at 77 K was studied. The radius of nonradiative energy transfer depends on the solvation of metal complexes of this series.

Key words

ligand-to-metal charge transfer luminescence phosphorescence triplet energy transfer exchange-resonant energy transfer organometallic π-complexes zirconium and hafnium complexes cyclopentadiene 

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Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  • G. V. Loukova
    • 1
  • V. P. Vasiliev
    • 1
  • V. A. Smirnov
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation

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