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Effect of the solvent on the radius of exchange interactions of d0-metal complexes with cyclopentadiene

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Abstract

The effect of solvent on the efficiency of exchange-resonant energy transfer from d0-organometallic π-complexes to nonphosphorescent cyclopentadiene in glassy organic solvents at 77 K was studied. The radius of nonradiative energy transfer depends on the solvation of metal complexes of this series.

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Correspondence to G. V. Loukova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1601–1604, August, 2009.

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Loukova, G.V., Vasiliev, V.P. & Smirnov, V.A. Effect of the solvent on the radius of exchange interactions of d0-metal complexes with cyclopentadiene. Russ Chem Bull 58, 1650–1653 (2009). https://doi.org/10.1007/s11172-009-0227-8

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  • DOI: https://doi.org/10.1007/s11172-009-0227-8

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