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Russian Chemical Bulletin

, Volume 58, Issue 7, pp 1353–1360 | Cite as

The synthesis, structure, and electron density distribution in crystals of 4,5-dihydroxyimidazolidine-2-thiones

  • Yu. V. Nelyubina
  • G. A. Gazieva
  • V. V. Baranov
  • P. A. Belyakov
  • A. O. Chizhov
  • K. A. Lyssenko
  • A. N. Kravchenko
Full Articles

Abstract

1,3-H2-, 1,3-Me2-, and 1,3-Et2-4,5-Dihydroxyimidazolidine-2-thiones were synthesized and their structural peculiarities were studied. A comparative analysis of dihydroxyimidazolidine-2-thione and its carbonyl analog performed in the framework of detailed investigation of the electron density distribution in the corresponding crystals revealed the reason for different number and geometric parameters of the hydrogen bonds formed by the (thio)carbonyl groups in the crystals.

Key words

cis- and trans-isomers 4,5-dihydroxyimidazolidine-2-thiones 1H and 13C NMR spectroscopy X-ray analysis electron density distribution function topological analysis 

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Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  • Yu. V. Nelyubina
    • 1
  • G. A. Gazieva
    • 2
  • V. V. Baranov
    • 2
  • P. A. Belyakov
    • 2
  • A. O. Chizhov
    • 2
  • K. A. Lyssenko
    • 1
  • A. N. Kravchenko
    • 2
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation

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