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Russian Chemical Bulletin

, Volume 58, Issue 6, pp 1315–1317 | Cite as

Temperature-programmed reduction of cobalt-containing catalysts of the Fischer-Tropsch synthesis based on ultrafine aluminum powders alloyed with rare-earth metals

  • A. S. Seleznev
  • L. A. Petrov
  • V. I. Kononenko
  • I. A. Chupova
  • A. V. Ryabina
Brief Communications

Abstract

The ultrafine aluminum powder alloyed with rare-earth metals (Ce, Sm), which is used as a support for the cobalt-containing catalysts of the Fischer-Tropsch synthesis, was studied by the temperature-programmed reduction method. The presence of rare-earth metals in the composition of the ultrafine aluminum powder changes the reduction process of cobalt oxides on the catalytic system surface.

Key words

cobalt-aluminum catalyst ultrafine alloys rare-earth metals temperature-programmed reduction Fischer-Tropsch synthesis of hydrocarbons 

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References

  1. 1.
    E. V. Slivinskii, A. E. Kuz’min, A. V. Abramova, G. A. Kliger, S. M. Loktev, Neftekhimiya, 1998, 38, 243 [Petroleum Chemistry (Engl. Transl.), 1998, 38].Google Scholar
  2. 2.
    R. B. Anderson. The Fischer-Tropsch Synthesis, Academic Press, London-New York, 1984, 301 pp.Google Scholar
  3. 3.
    US. Pat. 4657885; Chem. Abstrs., 1987, 106, 215884.Google Scholar
  4. 4.
    E. V. Lifanov, E. Kh. Kim, A. V. Toropova, F. A. Mil’man, O. A. Kolotygin, F. K. Shmidt, Zh. Fiz. Khim., 2004, 10, 1789 [Russ. J. Phys. Chem. (Engl. Transl.), 2004, 10].Google Scholar
  5. 5.
    P. Arnoldy, J. A. Moulijn, J. Catal., 1985, 93, 38.CrossRefGoogle Scholar
  6. 6.
    A. S. Seleznev, S. V. Erankin, L. A. Petrov, V. I. Kononenko, I. A. Chupova, Tez. dokl. XI Molodezhnoi konf. organicheskoi khimii, posvyashchennoi 110-letiyu so dnya rozhdeniya I. Ya. Postovskogo [Proc. XI Youth Conf. on Organic Chemistry Dedicated to the 110th Anniversary of I. Ya Postovsky] (Ekaterinburg, November 23–27), Ekaterinburg, 2008, 442 (in Russian).Google Scholar
  7. 7.
    A. L. Lapidus, Izv. Akad. Nauk, Ser. Khim., 1991, 12, 2681. [Russ. Chem. Bull. (Engl.Transl.), 1991, 12].Google Scholar
  8. 8.
    A. L. Lapidus, O. L. Eliseev, A. B. Erofeev, I. K. Kobrakov, L. V. Tishkova, Yu. A. Agafonov, Khim. Tverdogo Topliva [Chemistry of Solid Fuel], 2006, 4, 81 (in Russian).Google Scholar
  9. 9.
    V. I. Kononenko, I. A. Chupova, V. G. Shevchenko, O. N. Chupakhin, L. A. Petrov, A. S. Seleznev, Proc. 36th ISTC Japan Workshop on Catalysis in Russia/CIS, Japan, December 5, Tokyo, 2005, 58.Google Scholar

Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  • A. S. Seleznev
    • 1
  • L. A. Petrov
    • 1
  • V. I. Kononenko
    • 2
  • I. A. Chupova
    • 2
  • A. V. Ryabina
    • 2
  1. 1.I. Ya. Postovsky Institute of Organic SynthesisUral Branch of the Russian Academy of SciencesEkaterinburgRussian Federation
  2. 2.Institute of Solid State ChemistryUral Branch of the Russian Academy of SciencesEkaterinburgRussian Federation

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