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Russian Chemical Bulletin

, Volume 58, Issue 5, pp 1091–1093 | Cite as

Heterocyclization of hydrazine with acetaldehyde and H2S

  • V. R. Akhmetova
  • G. R. Nadyrgulova
  • N. N. Murzakova
  • Z. A. Starikova
  • M. Yu. Antipin
  • R. V. Kunakova
Brief Communications

Abstract

Hydrazine is regioselectively condensed with a mixture of acetaldehyde and H2S at a temperature below −10 °C to form 2,4,6,8-tetramethyl-3,7-dithia-1,5-diazabicyclo[3.3.0]-octane. The reaction at 0 °C with the reverse order of mixing of the starting reagents affords 2,4,6-trimethyl(1,3,5-dithiazinan-5-yl)amine as the major product.

Key words

heterocyclization hydrazine acetaldehyde hydrogen sulfide 2,4,6-trimethyl-(1,3,5-dithiazinan-5-yl)amine 2,4,6,8-tetramethyl-3,7-dithia-1,5-diazabicyclo[3.3.0]octane X-ray diffraction study 

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Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  • V. R. Akhmetova
    • 1
  • G. R. Nadyrgulova
    • 1
  • N. N. Murzakova
    • 1
  • Z. A. Starikova
    • 2
  • M. Yu. Antipin
    • 2
  • R. V. Kunakova
    • 1
  1. 1.Institute of Petrochemistry and CatalysisRussian Academy of SciencesUfaRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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