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Russian Chemical Bulletin

, Volume 58, Issue 1, pp 119–125 | Cite as

Aminopyridines as amino components in the catalytic synthesis of α-aminophosphonates

  • E. D. Matveeva
  • T. A. Podrugina
  • I. N. Kolesnikova
  • A. A. Borisenko
  • N. S. Zefirov
Full Articles

Abstract

6h-Aminophosphonates containing alicyclic, aromatic, and heterocyclic fragments were obtained in high yields by the Kabachnick—Fields reaction of the corresponding carbonyl compounds with 2-, 3- and 4-aminopyridines and diethyl phosphite using tetra- tert-butyl- phthalocyanine aluminum chloride as the catalyst. 2-, 3-, 4-Aminopyridines were found to vary in their reactivity with ketones and diethyl phosphite in the catalytic three-component one-pot process.

Key words

catalysis α-aminophosphonates the Kabachnick—Fields reaction tetra-tert-butylphthalocyanine aluminum chloride 2-, 3- 4-aminopyridines. 

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Copyright information

© Springer Science+Business Media, Inc.  2009

Authors and Affiliations

  • E. D. Matveeva
    • 1
  • T. A. Podrugina
    • 1
  • I. N. Kolesnikova
    • 1
  • A. A. Borisenko
    • 1
  • N. S. Zefirov
    • 1
  1. 1.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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