Abstract
The kinetics of oxidation of a series of alcohols (propan-2-ol, 2-methylpropan-1-ol, butan-1-ol, butan-2-ol, 3-methylpentan-1-ol, heptan-4-ol, decan-2-ol, cyclohexanol, borneol) by chlorine dioxide in organic solvents was studied using spectrophotometry. The reaction is described by the second-order rate equation w = k[ROH][ClO2]. The rate constants were measured in the range of 10–60 °C, and the activation parameters of the processes were calculated. The products were identified, and the yields were determined.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2283–2286, November, 2008.
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Ganieva, E.S., Ganiev, I.M., Grabovskiy, S.A. et al. Oxidation of alcohols by chlorine dioxide in organic solvents. Russ Chem Bull 57, 2328–2331 (2008). https://doi.org/10.1007/s11172-008-0330-2
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DOI: https://doi.org/10.1007/s11172-008-0330-2