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Russian Chemical Bulletin

, 57:2311 | Cite as

Diastereomeric P*-mono- and P*,P*-bidentate diamidophosphite ligands based on 1,4:3,6-dianhydro-d-mannitol in asymmetric metallocomplex catalysis

  • K. N. Gavrilov
  • S. V. Zheglov
  • P. A. Vologzhanin
  • E. A. Rastorguev
  • A. A. Shiryaev
  • M. G. Maksimova
  • S. E. Lyubimov
  • E. B. Benetsky
  • A. S. Safronov
  • P. V. Petrovskii
  • V. A. Davankov
  • B. Schäffner
  • A. Börner
Full Articles

Abstract

Synthesis of diastereomeric mono- and bidentate diamidophosphites bearing P*-stereo-centers and phosphabicyclo[3.3.0]octane backbone and their coordination with rhodium(i) and palladium(ii) are considered. Their use in Rh-catalyzed asymmetric allylation allowed one to achieve 87% ee values and the use in Rh-catalyzed asymmetric hydrogenation gave up to 98% ee.

Key words

P*-chiral diamidophosphites ligands rhodium complexes palladium complexes asymmetric allylation asymmetric hydrogenation deracemization 1,4:3,6-dianhydro-d-mannitol 

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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • K. N. Gavrilov
    • 1
  • S. V. Zheglov
    • 1
  • P. A. Vologzhanin
    • 1
  • E. A. Rastorguev
    • 1
  • A. A. Shiryaev
    • 1
  • M. G. Maksimova
    • 1
  • S. E. Lyubimov
    • 2
  • E. B. Benetsky
    • 2
  • A. S. Safronov
    • 2
  • P. V. Petrovskii
    • 2
  • V. A. Davankov
    • 2
  • B. Schäffner
    • 3
  • A. Börner
    • 3
  1. 1.Department of ChemistryS. A. Esenin Ryazan State UniversityRyazanRussian Federation
  2. 2.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  3. 3.Leibniz-Institut für KatalyseUniversität Rostock e.V.RostockGermany

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