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Russian Chemical Bulletin

, 57:2204 | Cite as

Dinuclear cage-like metalloorganosiloxane containing CrIII ions

  • A. N. Bilyachenko
  • A. A. Korlyukov
  • M. M. Levitskii
  • B. G. Zavin
  • M. Yu. Antipin
  • O. A. Filippov
  • V. I. Tsupreva
Brief Communications

Abstract

Cage-like chromium sodium phenylsiloxane (PhSiO1.5)12(CrO1.5)2(NaO0.5)6·3BuOH·9EtOH·2H2O containing two CrIII ions was prepared for the first time by the exchange reaction of sodium phenylsilanolate with CrCl3. The coordination sphere of the metal atom is filled by silanolate anions and water molecules located in the inner cavity of the cage. The structure of this compound was established by X-ray diffraction.

Key words

cage-like metalloorganosiloxanes X-ray diffraction analysis 

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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • A. N. Bilyachenko
    • 1
  • A. A. Korlyukov
    • 1
  • M. M. Levitskii
    • 1
  • B. G. Zavin
    • 1
  • M. Yu. Antipin
    • 1
  • O. A. Filippov
    • 1
  • V. I. Tsupreva
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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