Russian Chemical Bulletin

, 57:2198 | Cite as

Dodecanuclear NiII complex containing pivalate and hexafluoroacetylacetonate ligands

  • O. V. Kuznetsova
  • E. Yu. Fursova
  • V. I. Ovcharenko
  • G. V. Romanenko
  • A. S. Bogomyakov
Brief Communications


A dodecanuclear complex [Ni12Piv10(hfac)6(OH)8(EtOH)6]·C6H14 was isolated from various synthetic systems simultaneously containing NiII and the pivalate and hexafluoro-acetylacetonate anions. The structure of this complex was determined and the magnetic properties were investigated. The use of EtOH as the solvent or the presence of EtOH in the reagents is the decisive factor for the formation of this complex.

Key words

nickel(II) polynuclear compounds pivalates hexafluoroacetylacetonates X-ray diffraction study magnetic measurements 


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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • O. V. Kuznetsova
    • 1
  • E. Yu. Fursova
    • 1
  • V. I. Ovcharenko
    • 1
  • G. V. Romanenko
    • 1
  • A. S. Bogomyakov
    • 1
  1. 1.International Tomography CenterSiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation

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