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Dodecanuclear NiII complex containing pivalate and hexafluoroacetylacetonate ligands

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Abstract

A dodecanuclear complex [Ni12Piv10(hfac)6(OH)8(EtOH)6]·C6H14 was isolated from various synthetic systems simultaneously containing NiII and the pivalate and hexafluoro-acetylacetonate anions. The structure of this complex was determined and the magnetic properties were investigated. The use of EtOH as the solvent or the presence of EtOH in the reagents is the decisive factor for the formation of this complex.

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    O. V. Kuznetsova, E. Yu. Fursova, V. I. Ovcharenko, G. V. Romanenko & A. S. Bogomyakov

Authors
  1. O. V. Kuznetsova
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  2. E. Yu. Fursova
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  3. V. I. Ovcharenko
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  4. G. V. Romanenko
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  5. A. S. Bogomyakov
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Corresponding author

Correspondence to G. V. Romanenko.

Additional information

Dedicated to Academician B. A. Trofimov on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2156–2158, October, 2008.

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Kuznetsova, O.V., Fursova, E.Y., Ovcharenko, V.I. et al. Dodecanuclear NiII complex containing pivalate and hexafluoroacetylacetonate ligands. Russ Chem Bull 57, 2198–2200 (2008). https://doi.org/10.1007/s11172-008-0300-8

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  • DOI: https://doi.org/10.1007/s11172-008-0300-8

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