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Russian Chemical Bulletin

, Volume 57, Issue 8, pp 1653–1656 | Cite as

1,2,3,4,7-Pentamethylindenyl complex [(η5-C9H2Me5)RhI2]2 as a synthon for the [(η5-C9H2Me5)Rh]2+ fragment

  • D. A. Loginov
  • A. V. Vologzhanina
  • P. V. Petrovskii
  • M. M. Vinogradov
  • A. R. Kudinov
Full Articles

Abstract

The reaction of the iodide complex [(η5-C9H2Me5)RhI2]2 (1) or the acetonitrile complex [(η5-C9H2Me5)Rh(MeCN)3]2+ with Tl[Tl(η-7,8-C2B9H11)] afforded rhodacarborane (η5-C9H2Me5)Rh(7,8-C2B9H11) (2). The cationic triple-decker complex with the bridging boratabenzene ligand [Cp*Fe(μ-η:η-C5H3Me2BMe)Rh(η5-C9H2Me5)]2+ (3) was synthesized by the reaction of the nitromethane solvate [(η5-C9H2Me5)Rh(MeNO2)3]2+ with the sandwich compound Cp*Fe(η-C5H3Me2BMe). The structure of 2 was established by X-ray diffraction.

Key words

metallacarboranes sandwich compounds rhodium 

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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • D. A. Loginov
    • 1
  • A. V. Vologzhanina
    • 1
  • P. V. Petrovskii
    • 1
  • M. M. Vinogradov
    • 1
  • A. R. Kudinov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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