Advertisement

Russian Chemical Bulletin

, Volume 57, Issue 7, pp 1467–1476 | Cite as

Synthesis and spectroscopic study of the d-metal complexes with new octa(benzo-15-crown-5)-substituted phthalocyanine

  • N. M. Logacheva
  • V. E. Baulin
  • A. Yu. Tsivadze
  • T. V. Basova
  • L. A. Sheludyakova
Full Articles

Abstract

Octa(benzo-15-crown-5)-substituted phthalocyanine and its complexes with d-metals (NiII, CoII, CuII, ZnII, and CdII) have been synthesized for the first time. The compounds were studied by UV—Vis spectroscopy, MALDI-TOF mass spectrometry, NMR, ESR, IR spectroscopy, and Raman spectroscopy. The dependence of the spectral characteristics of the studied compounds on the ion radius of the complexing agent was demonstrated.

Key words

symmetric octasubstituted phthalocyanine crown ether d-metals metal complexes UV—Vis spectroscopy MALDI-TOF mass spectrometry NMR spectroscopy IR spectroscopy Raman spectroscopy electron spin resonance 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    C. C. Leznoff, A. B. P. Lever, Phthalocyanines. Properties and Application, VCH Publ. Inc., New York, 1989, 1990, 1–2.Google Scholar
  2. 2.
    J. Simon, J.-J. André, Molecular Semiconductors, Springer, Berlin, 1985.Google Scholar
  3. 3.
    A. Yu. Tsivadze, Usp. Khim., 2004, 73, 6 [Russ. Chem. Rev., 2004, 73, 5 (Engl. Transl.)].Google Scholar
  4. 4.
    N. Kobayashi, Y. Nishiyma, J. Chem. Soc., Chem. Commun., 1986, 1462.Google Scholar
  5. 5.
    N. Kobayashi, A. B. P. Lever, J. Am. Chem. Soc., 1987, 109, 7433.CrossRefGoogle Scholar
  6. 6.
    A. V. Nikolaitchik, O. Korth, M. A. J. Rodgers, J. Phys. Chem. A, 1999, 103, 7587.CrossRefGoogle Scholar
  7. 7.
    S. Sarigul, O. Bekaroglu, Chem. Ber., 1989, 122, 291.CrossRefGoogle Scholar
  8. 8.
    D. Wohrle, M. Eskes, K. Shigehara, A. A. Yamada, Synthesis, 1993, 194.Google Scholar
  9. 9.
    N. Kobayashi, Coord. Chem. Rev., 2001, 219–221, 99.CrossRefGoogle Scholar
  10. 10.
    K. Takahashi, J. Shimoda, J. Makoto, Y. Fuchita, H. Okawa, Chem. Lett., 1998, 2, 173.CrossRefGoogle Scholar
  11. 11.
    J. Jiang, R. Liu, T. Mak, T. Chan, D. Ng, Polyhedron, 1998, 16, 515.CrossRefGoogle Scholar
  12. 12.
    A. G. Martynov, Yu. G. Gorbunova, I. V. Khrapova, S. G. Sakharov, A. Yu. Tsivadze, Zh. Neorg. Khim., 2002, 47, 1616 [Russ. J. Inorg. Chem., 2002, 47, 1479 (Engl. Transl.)].Google Scholar
  13. 13.
    Yu. G. Gorbunova, L. A. Lapkina, A. G. Martynov, I. V. Biryukova, A. Yu. Tsivadze, Koord. Khim., 2004, 30, 263 [Russ. J. Coord. Chem., 2004, 30, 245 (Engl. Transl.)].Google Scholar
  14. 14.
    L. D. Rollmann, R. T. Iwamoto, J. Am. Chem. Soc., 1968, 90, 1455.CrossRefGoogle Scholar
  15. 15.
    B. M. Hoffman, D. L. Diemente, F. Basolo, J. Am. Chem. Soc., 1970, 92, 61.CrossRefGoogle Scholar
  16. 16.
    T. V. Basova, B. A. Kolesov, Zh. Strukt. Khim., 2000, 41, 940 [Russ. J. Struct. Chem., 2000, 41, 770 (Engl. Transl.)].Google Scholar
  17. 17.
    D. R. Tackley, G. Dent, W. E. Smith, Phys. Chem. Chem. Phys., 2000, 2, 3949.CrossRefGoogle Scholar
  18. 18.
    R. Aroca, Z. Q. Zeng, J. Mink, J. Phys. Chem. Solids, 1990, 51, 135.CrossRefGoogle Scholar
  19. 19.
    D. Battisti, L. Tomilova, R. Aroca, Chem. Mater., 1992, 4, 1323.CrossRefGoogle Scholar
  20. 20.
    M. L. Rodriquez, J. Souto, J. A. De Daja, J. Raman Spectr., 1995, 26, 693.CrossRefGoogle Scholar
  21. 21.
    H. Ding, S. Wang, S. Xi, J. Mol. Struct., 1999, 475, 175.CrossRefGoogle Scholar
  22. 22.
    W. E. Smith, B. N. Rospendowski, Raman Spectra of Phthalocyanines, in Phthalocyanines: Properties and Applications, Eds C. C. Leznoff, A. B. P. Lever, VCH, Weinheim, Germany, 1993, 3, 167.Google Scholar
  23. 23.
    D. R. Tackley, G. Dent, W. E. Smith, Phys. Chem. Chem. Phys., 2001, 3, 1419.CrossRefGoogle Scholar
  24. 24.
    A. V. Ziminov, S. M. Ramsh, E. I. Terukov, I. N. Trapeznikova, V. V. Shamanin, T. A. Yurre, Fiz. Tekhn. Poluprovodn., 2006, 40, 1161.Google Scholar
  25. 25.
    T. Kobayashi, F. Kurokawa, N. Uyeda, E. Suito, Spectrochim. Acta, Part A, 1970, 26, 1305.CrossRefGoogle Scholar
  26. 26.
    T. Kobayashi, Spectrochim. Acta, Part A, 1970, 26, 1313.CrossRefGoogle Scholar
  27. 27.
    A. Yu. Chernyad’ev, N. M. Logacheva, A. Yu. Tsivadze, Zh. Neorg. Khim., 2005, 50, 615 [Russ. J. Inorg. Chem., 2005, 50, 552 (Engl. Transl.)].Google Scholar

Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • N. M. Logacheva
    • 1
  • V. E. Baulin
    • 2
  • A. Yu. Tsivadze
    • 1
  • T. V. Basova
    • 3
  • L. A. Sheludyakova
    • 3
  1. 1.A. N. Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Institute of Physiologically Active CompoundsRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation
  3. 3.A. V. Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation

Personalised recommendations