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Synthesis and spectroscopic study of the d-metal complexes with new octa(benzo-15-crown-5)-substituted phthalocyanine

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Abstract

Octa(benzo-15-crown-5)-substituted phthalocyanine and its complexes with d-metals (NiII, CoII, CuII, ZnII, and CdII) have been synthesized for the first time. The compounds were studied by UV—Vis spectroscopy, MALDI-TOF mass spectrometry, NMR, ESR, IR spectroscopy, and Raman spectroscopy. The dependence of the spectral characteristics of the studied compounds on the ion radius of the complexing agent was demonstrated.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    N. M. Logacheva & A. Yu. Tsivadze

  2. Institute of Physiologically Active Compounds, Russian Academy of Sciences, 1 Severnyi proezd, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. E. Baulin

  3. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    T. V. Basova & L. A. Sheludyakova

Authors
  1. N. M. Logacheva
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  2. V. E. Baulin
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  3. A. Yu. Tsivadze
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  4. T. V. Basova
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  5. L. A. Sheludyakova
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Correspondence to N. M. Logacheva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1439–1447, July, 2008.

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Logacheva, N.M., Baulin, V.E., Tsivadze, A.Y. et al. Synthesis and spectroscopic study of the d-metal complexes with new octa(benzo-15-crown-5)-substituted phthalocyanine. Russ Chem Bull 57, 1467–1476 (2008). https://doi.org/10.1007/s11172-008-0190-9

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  • DOI: https://doi.org/10.1007/s11172-008-0190-9

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