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Synthesis and electrochemical study of 3- and 4-(2-pyridyl)-1,3-benzothiazole complexes with transition metals (CoII, NiII, and CuII). Molecular structure of bis{(4-(2-pyridyl)-1,3-benzothiazole)copper(ii)} tetraacetate

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Abstract

A series of the M(L)Cl2 · nH2O and {M(L)}2(OAc)4 complexes (M = NiII, CoII, and CuII; L is 3- and 4-(2-pyridyl)-1,3-benzothiazole) were synthesized by the reaction of L with MX2 · nH2O (X = Cl, OAc) in ethanol. The molecular and crystal structures of the CuL2(OAc)4 binuclear complex (L is 4-(2-pyridyl)benzothiazole) were determined by X-ray diffraction analysis. The copper atoms have a distorted tetragonal bipyramidal environment and are coordinated to the nitrogen atom of the pyridine moiety of the ligand and to two oxygen atoms of the bridging acetate ligands. The Cu-Cu distance is 2.6129(9) Å. The electrochemical behavior of the synthesized ligands and complexes was studied using the cyclic voltammetry and rotating disk electrode techniques in DMF solutions (0.1 M Bu4NClO4). The primary reduction of all the complexes under study is directed to the metal.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    E. K. Beloglazkina, I. V. Yudin, A. G. Mazhuga, A. A. Moiseeva, S. V. Zatonskii & N. V. Zyk

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  1. E. K. Beloglazkina
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  2. I. V. Yudin
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  3. A. G. Mazhuga
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  4. A. A. Moiseeva
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  5. S. V. Zatonskii
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  6. N. V. Zyk
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Correspondence to E. K. Beloglazkina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 565–571, March, 2008.

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Beloglazkina, E.K., Yudin, I.V., Mazhuga, A.G. et al. Synthesis and electrochemical study of 3- and 4-(2-pyridyl)-1,3-benzothiazole complexes with transition metals (CoII, NiII, and CuII). Molecular structure of bis{(4-(2-pyridyl)-1,3-benzothiazole)copper(ii)} tetraacetate. Russ Chem Bull 57, 577–584 (2008). https://doi.org/10.1007/s11172-008-0090-z

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  • DOI: https://doi.org/10.1007/s11172-008-0090-z

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