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Russian Chemical Bulletin

, Volume 57, Issue 1, pp 83–89 | Cite as

A kinetic model for limonene oxidation

  • L. M. Pisarenko
  • D. A. Krugovov
  • A. N. Shchegolikhin
  • O. T. Kasaikina
Full Articles

Abstract

The kinetic regularities of the autooxidation of R(+)−limonene (LH) were experimentally studied at various temperatures. A kinetic model including the main elementary reactions and the corresponding rate constants was developed. The degenerate chain branching during limonene oxidation proceeds via bimolecular reactions and involves hydroperoxide LOOH + LH → L· + LO· + H2O and LOOH + LOOH → LO· + LO2 · + H2O.

Key words

limonene liquid-phase oxidation hydroperoxides kinetic parameters kinetic model 

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Copyright information

© Springer Science+Business Media, Inc.  2008

Authors and Affiliations

  • L. M. Pisarenko
    • 1
  • D. A. Krugovov
    • 2
  • A. N. Shchegolikhin
    • 3
  • O. T. Kasaikina
    • 1
  1. 1.N. N. Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussian Federation
  2. 2.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation
  3. 3.N. M. Emanuel Institute of Biochemical PhysicsRussian Academy of SciencesMoscowRussian Federation

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