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Russian Chemical Bulletin

, Volume 56, Issue 11, pp 2255–2257 | Cite as

Alkyl 2-chloro-3,3,3-trifluoro-2-isocyanatopropionates

  • V. B. Sokolov
  • T. V. Goreva
  • T. A. Epishina
  • A. Yu. Aksinenko
Article

Abstract

Earlier unknown representatives of fluorine-containing α-chloroalkylisocyanates, viz., esters of 2-chloro-3,3,3-trifluoro-2-isocyanatopropionic acid, were obtained. Synthetic potentialities of these compounds in the preparation of 2-substituted derivatives of 3,3,3-trifluoroalanine were demonstrated.

Key words

trifluoropyruvates carbamates isocyanates amino acids aminals alcohols anilines phosphorus pentachloride organofluorine compounds 

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References

  1. 1.
    V. I. Gorbatenko and L. I. Samarai, Synthesis, 1980, 85.Google Scholar
  2. 2.
    L. I. Samarai, V. I. Gorbatenko, and M. V. Vovk, Ukr. Khim. Zh. [Ukrainian Chem. J.], 1989, 85, 966 (in Russian).Google Scholar
  3. 3.
    O. V. Korenchenko, A. Yu. Aksinenko, V. B. Sokolov, and I. V. Martynov, J. Fluorine Chem., 1991, 54, 412.CrossRefGoogle Scholar
  4. 4.
    O. V. Korenchenko, V. B. Sokolov, A. Yu. Aksinenko, and I. V. Martynov, Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 373 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 39, 313 (Engl. Transl.)].Google Scholar
  5. 5.
    C. W. Fearon, J. A. Rodkey, and R. H. Abeles, Biochemistry, 1982, 21, 3790.CrossRefGoogle Scholar
  6. 6.
    V. B. Sokolov and A. Yu. Aksinenko, Izv. Akad. Nauk, Ser. Khim., 2003, 2053 [Russ. Chem. Bull., Int. Ed., 2003, 52, 2167].Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • V. B. Sokolov
    • 1
  • T. V. Goreva
    • 1
  • T. A. Epishina
    • 1
  • A. Yu. Aksinenko
    • 1
  1. 1.Institute of Physiologically Active CompoundsRussian Academy of SciencesChernogolovka, Moscow RegionRussian Federation

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