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Russian Chemical Bulletin

, Volume 56, Issue 9, pp 1849–1856 | Cite as

Functionalization of sterically hindered o-benzoquinones: amino-substituted 3,6-di(tert-butyl)-o-benzoquinones

  • G. A. Abakumov
  • V. K. Cherkasov
  • T. N. Kocherova
  • N. O. Druzhkov
  • Yu. A. Kurskii
  • M. P. Bubnov
  • G. K. Fukin
  • L. G. Abakumova
Article

Abstract

New sterically hindered functionalized o-quinones were synthesized by the 1,4-nucleophilic addition of secondary cyclic amines to 3,6-di(tert-butyl)-o-benzoquinone. The ability of these o-quinones to form o-semiquinone complexes with transition and main-group metals was studied by ESR spectroscopy in solution.

Key words

o-quinones amines piperazines nucleophilic addition o-semiquinone metal complexes charge transfer band ESR spectroscopy 

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Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • G. A. Abakumov
    • 1
  • V. K. Cherkasov
    • 1
  • T. N. Kocherova
    • 1
  • N. O. Druzhkov
    • 1
  • Yu. A. Kurskii
    • 1
  • M. P. Bubnov
    • 1
  • G. K. Fukin
    • 1
  • L. G. Abakumova
    • 1
  1. 1.G. A. Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussian Federation

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