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Russian Chemical Bulletin

, Volume 56, Issue 6, pp 1149–1155 | Cite as

Synthesis and inhibitory activity of alkyl(hydroxyaryl)amines

  • O. I. Dyubchenko
  • V. V. Nikulina
  • E. I. Terakh
  • A. E. Prosenko
  • I. A. Grigor’ev
Article

Abstract

The reaction of ω-(4-hydroxyaryl)haloalkanes with various nitrogen-containing agents afforded primary, secondary, and tertiary amino derivatives of 2,6-dialkylphenols. For the compounds synthesized, the reaction rate constants with peroxide radicals were measured for cumene and methyl oleate oxidation. The total inhibitory activity in the model reactions of thermal autooxidation of lard and hexadecane was studied. The rate constants of alkyl(hydroxylaryl)amines are the same as those of the corresponding alkylphenols, whereas the total inhibitory activity of some alkyl(hydroxylaryl)amines exceeds substantially that for alkylphenols.

Key words

2,6-dialkylphenols ω-(4-hydroxyaryl)haloalkanes alkyl(hydroxylaryl)amines aminoalkylphenols antioxidation activity peroxide radicals total inhibitory activity 

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Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • O. I. Dyubchenko
    • 1
  • V. V. Nikulina
    • 1
  • E. I. Terakh
    • 1
  • A. E. Prosenko
    • 1
  • I. A. Grigor’ev
    • 2
  1. 1.Research Institute of Antioxidant ChemistryNovosibirsk State Pedagogical UniversityNovosibirskRussian Federation
  2. 2.N. N. Vorozhtsov Novosibirsk Institute of Organic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation

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