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Russian Chemical Bulletin

, Volume 55, Issue 11, pp 2056–2060 | Cite as

New method for the synthesis and the mechanism of formation of 1,2-di-and 1,2,3-trialkyldiaziridines

  • V. V. Kuznetsov
  • V. B. Ovchinnikova
  • V. P. Ananikov
  • N. N. Makhova
Article

Abstract

A new simple approach to the synthesis of 1,2-di-and 1,2,3-trialkyldiaziridines has been developed based on direct chlorination of a mixture of the corresponding aldehyde and an excess of primary aliphatic amine in water. The mechanism of this reaction is proposed and confirmed by quantum chemical calculations at the density functional theory level.

Key words

1,2-di-and 1,2,3-trialkyldiaziridines direct chlorination aldehydes primary aliphatic amines mechanism quantum chemical calculations B3LYP PCM 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • V. V. Kuznetsov
    • 1
  • V. B. Ovchinnikova
    • 2
  • V. P. Ananikov
    • 1
  • N. N. Makhova
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Russian Scientific Center “Applied Chemistry”St. PetersburgRussian Federation

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