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Russian Chemical Bulletin

, Volume 55, Issue 7, pp 1297–1299 | Cite as

A new method for the preparation of solution of sodium pentaphosphacyclopentadienide

  • V. A. Milyukov
  • A. V. Kataev
  • O. G. Sinyashin
  • E. Hey-Hawkins
Article

Abstract

Heating of a mixture of white phosphorus and sodium in diethylene glycol dimethyl ether in the presence of catalytic amounts of dibenzo-18-crown-6 affords a pure solution of sodium pentaphosphacyclopentadienide NaP5. One of the intermediate products is trisodium heptaphosphide Na3P7. The influence of the nature of a metal (Li, Na, K) on the formation of the pentaphosphacyclopentadienide anion was studied.

Key words

homopolyatomic clusters polyphosphides pentaphosphacyclopentadienide anion white phosphorus alkaline metals phase transfer catalysis 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • V. A. Milyukov
    • 1
  • A. V. Kataev
    • 1
  • O. G. Sinyashin
    • 1
  • E. Hey-Hawkins
    • 2
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research CenterRussian Academy of SciencesKazanRussian Federation
  2. 2.Institute of Inorganic ChemistryUniversity of LeipzigLeipzigGermany

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