Abstract
Heating of a mixture of white phosphorus and sodium in diethylene glycol dimethyl ether in the presence of catalytic amounts of dibenzo-18-crown-6 affords a pure solution of sodium pentaphosphacyclopentadienide NaP5. One of the intermediate products is trisodium heptaphosphide Na3P7. The influence of the nature of a metal (Li, Na, K) on the formation of the pentaphosphacyclopentadienide anion was studied.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1249–1251, July, 2006.
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Milyukov, V.A., Kataev, A.V., Sinyashin, O.G. et al. A new method for the preparation of solution of sodium pentaphosphacyclopentadienide. Russ Chem Bull 55, 1297–1299 (2006). https://doi.org/10.1007/s11172-006-0414-9
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DOI: https://doi.org/10.1007/s11172-006-0414-9