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Russian Chemical Bulletin

, Volume 55, Issue 7, pp 1163–1170 | Cite as

Facile method for the synthesis of ruthenacarboranes, diamagnetic 3,3-[Ph2P(CH2)nPPh2]-3-H-3-Cl-closo-3,1,2-RuC2B9H11 (n = 3 or 4) and paramagnetic 3,3-[Ph2P(CH2)nPPh2]-3-Cl-closo-3,1,2-RuC2B9H11 (n = 2 or 3), as efficient initiators of controlled radical polymerization of vinyl monomers

  • D. N. Cheredilin
  • F. M. Dolgushin
  • I. D. Grishin
  • E. V. Kolyakina
  • A. S. Nikiforov
  • S. P. Solodovnikov
  • M. M. Il’in
  • V. A. Davankov
  • I. T. Chizhevsky
  • D. F. Grishin
Article

Abstract

A facile preparative procedure was developed for the synthesis of 17-and 18-electron closo-(diphosphine)ruthenacarborane complexes. This method is based on the replacement of PPh3 ligands with bis(diphenylphosphino)alkanes Ph2P(CH2)nPPh2 (n = 2—4) in ruthenacarborane 3,3-(PPh3)2-3-Cl-3-H-closo-3,1,2-RuC2B9H11. The resulting complexes exhibit high activity in controlled radical polymerization of vinyl monomers.

Key words

bis(diphenylphosphino)alkanes ruthenium carborane complexes synthesis controlled radical polymerization vinyl monomers 

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References

  1. 1.
    D. N. Cheredilin, R. Kadyrov, F. M. Dolgushin, E. V. Balagurova, I. A. Godovikov, S. P. Solodovnikov, and I. T. Chizhevsky, Inorg. Chem. Commun., 2005, 8, 614.CrossRefGoogle Scholar
  2. 2.
    D. N. Cheredilin, E. V. Balagurova, I. A. Godovikov, S. P. Solodovnikov, and I. T. Chizhevsky, Izv. Akad. Nauk, Ser. Khim., 2005, 2455 [Russ. Chem. Bull., Int. Ed., 2005, 54, 2535].Google Scholar
  3. 3.
    D. N. Cheredilin, F. M. Dolgushin, A. A. Korlyukov, I. A. Godovikov, R. Kadyrov, E. V. Balagurova, S. P. Solodovnikov, and I. T. Chizhevsky, J. Organomet. Chem., 2006, 691, 3989.CrossRefGoogle Scholar
  4. 4.
    D. N. Cheredilin, F. M. Dolgushin, E. V. Balagurova, I. A. Godovikov, and I. T. Chizhevsky, Izv. Akad. Nauk, Ser. Khim., 2004, 2000 [Russ. Chem. Bull., Int. Ed., 2004, 53, 2086].Google Scholar
  5. 5.
    E. V. Kolyakina, I. D. Grishin, D. N. Cheredilin, F. M. Dolgushin, I. T. Chizhevsky, and D. F. Grishin, Izv. Akad. Nauk, Ser. Khim., 2006, 85 [Russ. Chem. Bull., Int. Ed., 2006, 55 89].Google Scholar
  6. 6.
    M. Kamigaito, T. Ando, and M. Sawamoto, Chem. Rev., 2001, 101, 3689.CrossRefGoogle Scholar
  7. 7.
    K. Matyjaszewski and J. Xia, Chem. Rev., 2001, 101, 2921.CrossRefGoogle Scholar
  8. 8.
    E. H. S. Wong and M. F. Hawthorne, Inorg. Chem., 1978, 17, 2863.CrossRefGoogle Scholar
  9. 9.
    I. T. Chizhevsky, V. I. Bregadze, P. V. Petrovskii, A. V. Polyakov, A. I. Yanovskii, and Yu. T. Struchkov, Metalloorg. Khim., 1991, 4, 957 [Organomet. Chem. USSR, 1991, 4, 469 (Engl. Transl.)].Google Scholar
  10. 10.
    I. T. Chizhevsky, I. A. Lobanova, V. I. Bregadze, P. V. Petrovskii, V. A. Antonovich, A. V. Polyakov, A. I. Yanovsky, and Yu. T. Struchkov, Mendeleev. Commun., 1991, 47.Google Scholar
  11. 11.
    I. V. Pisareva, F. M. Dolgushin, O. L. Tok, V. E. Konoplev, K. Yu. Suponitsky, A. I. Yanovsky, and I. T. Chizhevsky, Organometallics, 2001, 20, 4216.CrossRefGoogle Scholar
  12. 12.
    I. T. Chizhevsky, I. A. Lobanova, P. V. Petrovskii, V. I. Bregadze, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, A. L. Chistyakov, I. V. Stankevich, C. B. Knobler, and M. F. Hawthorne, Organometallics, 1999, 18, 726.CrossRefGoogle Scholar
  13. 13.
    H. Takahashi, T. Ando, M. Kamigaito, and M. Sawamoto, Macromolecules, 1999, 32, 3820.CrossRefGoogle Scholar
  14. 14.
    T. Ando, M. Kamigaito, and M. Sawamoto, Macromolecules, 2000, 33, 5825.CrossRefGoogle Scholar
  15. 15.
    Y. Watanabe, T. Ando, M. Kamigaito, and M. Sawamoto, Macromolecules, 2001, 34, 4370.CrossRefGoogle Scholar
  16. 16.
    F. Simal, S. Sebille, A. Demonceau, A. F. Noels, R. Núñez, M. Abad, F. Teixidor, and C. Viñas, Tetrahedron Lett., 2000, 41, 5347.CrossRefGoogle Scholar
  17. 17.
    O. Tutusaus, S. Delfosse, F. Simal, A. Demonceau, A. F. Noels, R. Núñez, C. Viñas, and F. Teixidor, Inorg. Chem. Commun., 2002, 5, 941.CrossRefGoogle Scholar
  18. 18.
    G. M. Sheldrick, SHELXTL-97, V.5.10, Bruker AXS Inc., Madison (WI-53719, USA), 1997.Google Scholar
  19. 19.
    Entsiklopediya polimerov [Encyclopedia of Polymers], Sov. Entsiklopediya, Moscow, 1972, 1, p. 932 (in Russian).Google Scholar
  20. 20.
    B. G. Belen’kii and L. Z. Vilenchik, Khromatografiya polimerov [Chromatography of Polymers], Khimiya, Moscow, 1978, p. 344 (in Russian).Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • D. N. Cheredilin
    • 1
  • F. M. Dolgushin
    • 1
  • I. D. Grishin
    • 2
  • E. V. Kolyakina
    • 2
  • A. S. Nikiforov
    • 1
  • S. P. Solodovnikov
    • 1
  • M. M. Il’in
    • 1
  • V. A. Davankov
    • 1
  • I. T. Chizhevsky
    • 1
  • D. F. Grishin
    • 2
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.Nizhny Novgorod N. I. Lobachevsky State UniversityNizhny NovgorodRussian Federation

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