Abstract
Three new coordination compounds [{Zn(H2O)2} {Zn(H2O)4} Re4Te4(CN)12] (1), [Zn(en)2(NH3)2][{Zn(en)(NH3)2} Re4Te4(CN)12]·H2O (2), and [{Zn2(dien)3} Re4Te4(CN)12]· ·6H2O (3) (dien is diethylenetriamine) were prepared by reactions of aqueous solutions of the tetrahedral cluster rhenium tellurocyanide complex K4[Re4Te4(CN)12]· 5H2O with zinc dichloride in the presence of ammonia, ethylenediamine, and diethylenetriamine, respectively. Complex 1 has a three-dimensional structure with two types of the Zn atoms; complex 2 is ionic with the polymeric chain anion; complex 3 has a molecular structure. The structures of complexes 1–3 were determined by single-crystal X-ray diffraction analysis.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 718–721, April, 2006.
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Mironov, Y.V., Efremova, O.A., Naumov, D.Y. et al. Coordination compounds based on the cluster anion [Re4Te4(CN)12]4− and Zn2+ cation. Russ Chem Bull 55, 744–747 (2006). https://doi.org/10.1007/s11172-006-0324-x
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DOI: https://doi.org/10.1007/s11172-006-0324-x