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Russian Chemical Bulletin

, Volume 55, Issue 4, pp 744–747 | Cite as

Coordination compounds based on the cluster anion [Re4Te4(CN)12]4− and Zn2+ cation

  • Yu. V. Mironov
  • O. A. Efremova
  • D. Yu. Naumov
  • V. E. Fedorov
Article

Abstract

Three new coordination compounds [{Zn(H2O)2} {Zn(H2O)4} Re4Te4(CN)12] (1), [Zn(en)2(NH3)2][{Zn(en)(NH3)2} Re4Te4(CN)12]·H2O (2), and [{Zn2(dien)3} Re4Te4(CN)12]· ·6H2O (3) (dien is diethylenetriamine) were prepared by reactions of aqueous solutions of the tetrahedral cluster rhenium tellurocyanide complex K4[Re4Te4(CN)12]· 5H2O with zinc dichloride in the presence of ammonia, ethylenediamine, and diethylenetriamine, respectively. Complex 1 has a three-dimensional structure with two types of the Zn atoms; complex 2 is ionic with the polymeric chain anion; complex 3 has a molecular structure. The structures of complexes 1–3 were determined by single-crystal X-ray diffraction analysis.

Key words

rhenium tetrahedral chalcocyanide clusters zinc cyanide bridges coordination polymers polydentate amines crystal structure 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • Yu. V. Mironov
    • 1
  • O. A. Efremova
    • 2
  • D. Yu. Naumov
    • 1
  • V. E. Fedorov
    • 2
  1. 1.A. V. Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation
  2. 2.Novosibirsk State UniversityNovosibirskRussian Federation

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