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Russian Chemical Bulletin

, Volume 54, Issue 9, pp 2087–2093 | Cite as

Selective synthesis and spectroscopic properties of alkyl-substituted lanthanide(III) mono-, di-, and triphthalocyanines

  • V. E. Pushkarev
  • M. O. Breusova
  • E. V. Shulishov
  • Yu. V. Tomilov
Article

Abstract

Methods for the selective synthesis of mono-(RPcLnOAc), di-(RPc2Ln), and triphthalocyanines (RPc3Ln2) of rare-earth metals (Ln = Lu, Er, Eu) from symmetrically substituted 2,3,9,10,16,17,23,24-octaalkylphthalocyanines RPcH2 (R = Et, Bu) were developed. The synthesized complexes were characterized by NMR spectroscopy, mass spectrometry, and electronic absorption spectra. The conditions for 1H NMR spectra recording were optimized. Regularities in changing the spectral properties of the synthesized compounds, depending on the lanthanide nature and the planarity of metal phthalocyanine complexes, were found.

Key words

phthalocyanines rare-earth metals selective methods of synthesis 1H NMR spectra electronic absorption spectra 

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Copyright information

© Springer Science+Business Media, Inc. 2005

Authors and Affiliations

  • V. E. Pushkarev
    • 1
  • M. O. Breusova
    • 2
  • E. V. Shulishov
    • 1
  • Yu. V. Tomilov
    • 1
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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