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Selective synthesis and spectroscopic properties of alkyl-substituted lanthanide(III) mono-, di-, and triphthalocyanines

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Abstract

Methods for the selective synthesis of mono-(RPcLnOAc), di-(RPc2Ln), and triphthalocyanines (RPc3Ln2) of rare-earth metals (Ln = Lu, Er, Eu) from symmetrically substituted 2,3,9,10,16,17,23,24-octaalkylphthalocyanines RPcH2 (R = Et, Bu) were developed. The synthesized complexes were characterized by NMR spectroscopy, mass spectrometry, and electronic absorption spectra. The conditions for 1H NMR spectra recording were optimized. Regularities in changing the spectral properties of the synthesized compounds, depending on the lanthanide nature and the planarity of metal phthalocyanine complexes, were found.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. E. Pushkarev, E. V. Shulishov & Yu. V. Tomilov

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119992, Moscow, Russian Federation

    M. O. Breusova

Authors
  1. V. E. Pushkarev
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  2. M. O. Breusova
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  3. E. V. Shulishov
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  4. Yu. V. Tomilov
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Dedicated to Academician A. L. Buchachenko on the occasion of his 70th birthday.

tom@org.chem.msu.su

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2024–2030, September, 2005.

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Pushkarev, V.E., Breusova, M.O., Shulishov, E.V. et al. Selective synthesis and spectroscopic properties of alkyl-substituted lanthanide(III) mono-, di-, and triphthalocyanines. Russ Chem Bull 54, 2087–2093 (2005). https://doi.org/10.1007/s11172-006-0081-x

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  • DOI: https://doi.org/10.1007/s11172-006-0081-x

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