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Carbofunctional fluorine-containing triethoxysilanes: synthesis, film forming and properties

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Abstract

Novel fluorine-containing carbofunctional organosilicon monomers were synthesized: 3-pentafluorobenzylideneaminopropylethoxysilane (EtO)3Si(CH2)3N=CH-C6F5, N-3-methoxydiethoxysilylpropyltrifluoroacetamide (EtO)2(MeO)Si(CH2)3NHC(O)CF3, and 1,1,5-trihydrooctafluoroamyl N-3-triethoxysilylpropylaminopropanoate (EtO)3Si(CH2)3NH(CH2)2C(O)OCH2(CF2)3CHF2. Compositions for the formation of transparent thermally stable films were prepared from these monomers. The films have low absorbance intensity near 1550 nm, i.e., in the region of photosignal transmission of modern optical communication systems. The compositions can dissolve complexes with organofluorine ligands and produce transparent homogeneous films doped with rare-earth metals. The concentrations of the complexes in the matrices are 3.7–21.4 wt.% (metal concentrations are 0.6–3.7%). Fluorescence and fluorescence excitation spectra of the matrices and electronic absorption spectra of the doped films were studied.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    E. Yu. Ladilina, V. V. Semenov, Yu. A. Kurskii, O. V. Kuznetsova & M. A. Lopatin

  2. B. I. Stepanov Institute of Physics, National Academy of Sciences of Republic Belarus', 68 prosp. F. Skorina, 220072, Minsk, Republic Belarus'

    B. A. Bushuk & S. B. Bushuk

  3. Chemical Laboratory of Molecular Organization of Solid State, French Academy of Sciences, Montpellier II University, 34095, Montpellier, France

    W. E. Douglas

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  1. E. Yu. Ladilina
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  2. V. V. Semenov
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  3. Yu. A. Kurskii
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1131–1138, May, 2005.

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Ladilina, E.Y., Semenov, V.V., Kurskii, Y.A. et al. Carbofunctional fluorine-containing triethoxysilanes: synthesis, film forming and properties. Russ Chem Bull 54, 1160–1168 (2005). https://doi.org/10.1007/s11172-005-0375-4

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  • DOI: https://doi.org/10.1007/s11172-005-0375-4

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